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Latent ruthenium–indenylidene catalysts bearing a N-heterocyclic carbene and a bidentate picolinate ligand

A silver-free methodology was developed for the synthesis of unprecedented N-heterocyclic carbene ruthenium indenylidene complexes bearing a bidentate picolinate ligand. The highly stable (SIPr)(picolinate)RuCl(indenylidene) complex 4a (SIPr = 1,3-bis(2-6-diisopropylphenyl)imidazolidin-2-ylidene) de...

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Detalles Bibliográficos
Autores principales:	Schmid, Thibault E, Modicom, Florian, Dumas, Adrien, Borré, Etienne, Toupet, Loic, Baslé, Olivier, Mauduit, Marc
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Beilstein-Institut 2015
Materias:	Full Research Paper
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4578404/ https://www.ncbi.nlm.nih.gov/pubmed/26425213 http://dx.doi.org/10.3762/bjoc.11.169

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