Ruthenium indenylidene “1(st) generation” olefin metathesis catalysts containing triisopropyl phosphite

The reaction of triisopropyl phosphite with phosphine-based indenylidene pre-catalysts affords “1(st) generation” cis-complexes. These have been used in olefin metathesis reactions. The cis-Ru species exhibit noticeable differences with the trans-Ru parent complexes in terms of structure, thermal st...

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Autores principales: Guidone, Stefano, Nahra, Fady, Slawin, Alexandra M Z, Cazin, Catherine S J
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2015
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4578444/
https://www.ncbi.nlm.nih.gov/pubmed/26425210
http://dx.doi.org/10.3762/bjoc.11.166
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author Guidone, Stefano
Nahra, Fady
Slawin, Alexandra M Z
Cazin, Catherine S J
author_facet Guidone, Stefano
Nahra, Fady
Slawin, Alexandra M Z
Cazin, Catherine S J
author_sort Guidone, Stefano
collection PubMed
description The reaction of triisopropyl phosphite with phosphine-based indenylidene pre-catalysts affords “1(st) generation” cis-complexes. These have been used in olefin metathesis reactions. The cis-Ru species exhibit noticeable differences with the trans-Ru parent complexes in terms of structure, thermal stability and reactivity. Experimental data underline the importance of synergistic effects between phosphites and L-type ligands.
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spelling pubmed-45784442015-09-30 Ruthenium indenylidene “1(st) generation” olefin metathesis catalysts containing triisopropyl phosphite Guidone, Stefano Nahra, Fady Slawin, Alexandra M Z Cazin, Catherine S J Beilstein J Org Chem Full Research Paper The reaction of triisopropyl phosphite with phosphine-based indenylidene pre-catalysts affords “1(st) generation” cis-complexes. These have been used in olefin metathesis reactions. The cis-Ru species exhibit noticeable differences with the trans-Ru parent complexes in terms of structure, thermal stability and reactivity. Experimental data underline the importance of synergistic effects between phosphites and L-type ligands. Beilstein-Institut 2015-09-01 /pmc/articles/PMC4578444/ /pubmed/26425210 http://dx.doi.org/10.3762/bjoc.11.166 Text en Copyright © 2015, Guidone et al. https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Full Research Paper
Guidone, Stefano
Nahra, Fady
Slawin, Alexandra M Z
Cazin, Catherine S J
Ruthenium indenylidene “1(st) generation” olefin metathesis catalysts containing triisopropyl phosphite
title Ruthenium indenylidene “1(st) generation” olefin metathesis catalysts containing triisopropyl phosphite
title_full Ruthenium indenylidene “1(st) generation” olefin metathesis catalysts containing triisopropyl phosphite
title_fullStr Ruthenium indenylidene “1(st) generation” olefin metathesis catalysts containing triisopropyl phosphite
title_full_unstemmed Ruthenium indenylidene “1(st) generation” olefin metathesis catalysts containing triisopropyl phosphite
title_short Ruthenium indenylidene “1(st) generation” olefin metathesis catalysts containing triisopropyl phosphite
title_sort ruthenium indenylidene “1(st) generation” olefin metathesis catalysts containing triisopropyl phosphite
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4578444/
https://www.ncbi.nlm.nih.gov/pubmed/26425210
http://dx.doi.org/10.3762/bjoc.11.166
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