Role of TBATB in nano indium oxide catalyzed C-S bond formation

Nano sized indium oxide is found to be an efficient catalyst for the conversion of thiols to sulfides using Na(2)CO(3) as base and TBATB as reagent in DMSO at 110 °C. Here in situ generation of bromo intermediate by TBATB takes place through indium surface. A variety of aryl sulfides can be synthesi...

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Autores principales: Gogoi, Prasanta, Hazarika, Sukanya, Barman, Pranjit
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2015
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4586445/
https://www.ncbi.nlm.nih.gov/pubmed/26415729
http://dx.doi.org/10.1038/srep13873
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author Gogoi, Prasanta
Hazarika, Sukanya
Barman, Pranjit
author_facet Gogoi, Prasanta
Hazarika, Sukanya
Barman, Pranjit
author_sort Gogoi, Prasanta
collection PubMed
description Nano sized indium oxide is found to be an efficient catalyst for the conversion of thiols to sulfides using Na(2)CO(3) as base and TBATB as reagent in DMSO at 110 °C. Here in situ generation of bromo intermediate by TBATB takes place through indium surface. A variety of aryl sulfides can be synthesized in excellent yields from less reactive chlorides, boronic acids and thiols.
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spelling pubmed-45864452015-09-30 Role of TBATB in nano indium oxide catalyzed C-S bond formation Gogoi, Prasanta Hazarika, Sukanya Barman, Pranjit Sci Rep Article Nano sized indium oxide is found to be an efficient catalyst for the conversion of thiols to sulfides using Na(2)CO(3) as base and TBATB as reagent in DMSO at 110 °C. Here in situ generation of bromo intermediate by TBATB takes place through indium surface. A variety of aryl sulfides can be synthesized in excellent yields from less reactive chlorides, boronic acids and thiols. Nature Publishing Group 2015-09-29 /pmc/articles/PMC4586445/ /pubmed/26415729 http://dx.doi.org/10.1038/srep13873 Text en Copyright © 2015, Macmillan Publishers Limited http://creativecommons.org/licenses/by/4.0/ This work is licensed under a Creative Commons Attribution 4.0 International License. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in the credit line; if the material is not included under the Creative Commons license, users will need to obtain permission from the license holder to reproduce the material. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/
spellingShingle Article
Gogoi, Prasanta
Hazarika, Sukanya
Barman, Pranjit
Role of TBATB in nano indium oxide catalyzed C-S bond formation
title Role of TBATB in nano indium oxide catalyzed C-S bond formation
title_full Role of TBATB in nano indium oxide catalyzed C-S bond formation
title_fullStr Role of TBATB in nano indium oxide catalyzed C-S bond formation
title_full_unstemmed Role of TBATB in nano indium oxide catalyzed C-S bond formation
title_short Role of TBATB in nano indium oxide catalyzed C-S bond formation
title_sort role of tbatb in nano indium oxide catalyzed c-s bond formation
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4586445/
https://www.ncbi.nlm.nih.gov/pubmed/26415729
http://dx.doi.org/10.1038/srep13873
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