Giant Rugby Ball [{Cp(Bn)Fe(η(5)-P(5))}(24)Cu(96)Br(96)] Derived from Pentaphosphaferrocene and CuBr(2)

[Image: see text] The self-assembly of [Cp(Bn)Fe(η(5)-P(5))] (Cp(Bn) = η(5)-C(5)(CH(2)Ph)(5)) with CuBr(2) leads to the formation of an unprecedented rugby ball-shaped supramolecule consisting of 24 units of the pentaphosphaferrocene and an extended CuBr framework, which does not follow the fulleren...

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Autores principales: Heindl, Claudia, Peresypkina, Eugenia V., Virovets, Alexander V., Kremer, Werner, Scheer, Manfred
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2015
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4593573/
https://www.ncbi.nlm.nih.gov/pubmed/26280785
http://dx.doi.org/10.1021/jacs.5b06835
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author Heindl, Claudia
Peresypkina, Eugenia V.
Virovets, Alexander V.
Kremer, Werner
Scheer, Manfred
author_facet Heindl, Claudia
Peresypkina, Eugenia V.
Virovets, Alexander V.
Kremer, Werner
Scheer, Manfred
author_sort Heindl, Claudia
collection PubMed
description [Image: see text] The self-assembly of [Cp(Bn)Fe(η(5)-P(5))] (Cp(Bn) = η(5)-C(5)(CH(2)Ph)(5)) with CuBr(2) leads to the formation of an unprecedented rugby ball-shaped supramolecule consisting of 24 units of the pentaphosphaferrocene and an extended CuBr framework, which does not follow the fullerene topology. The resulting scaffold of 312 noncarbon atoms reveals three different coordination modes of the cyclo-P(5) ligand including a novel π-coordination. The outer dimensions of 3.7 × 4.6 nm of the sphere approach the range of the size of proteins. With a value of 32.1 nm(3), it is 62 times larger in volume than a C(60) molecule. Surprisingly, this giant rugby ball is also slightly soluble in CH(2)Cl(2).
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spelling pubmed-45935732015-10-09 Giant Rugby Ball [{Cp(Bn)Fe(η(5)-P(5))}(24)Cu(96)Br(96)] Derived from Pentaphosphaferrocene and CuBr(2) Heindl, Claudia Peresypkina, Eugenia V. Virovets, Alexander V. Kremer, Werner Scheer, Manfred J Am Chem Soc [Image: see text] The self-assembly of [Cp(Bn)Fe(η(5)-P(5))] (Cp(Bn) = η(5)-C(5)(CH(2)Ph)(5)) with CuBr(2) leads to the formation of an unprecedented rugby ball-shaped supramolecule consisting of 24 units of the pentaphosphaferrocene and an extended CuBr framework, which does not follow the fullerene topology. The resulting scaffold of 312 noncarbon atoms reveals three different coordination modes of the cyclo-P(5) ligand including a novel π-coordination. The outer dimensions of 3.7 × 4.6 nm of the sphere approach the range of the size of proteins. With a value of 32.1 nm(3), it is 62 times larger in volume than a C(60) molecule. Surprisingly, this giant rugby ball is also slightly soluble in CH(2)Cl(2). American Chemical Society 2015-08-17 2015-09-02 /pmc/articles/PMC4593573/ /pubmed/26280785 http://dx.doi.org/10.1021/jacs.5b06835 Text en Copyright © 2015 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Heindl, Claudia
Peresypkina, Eugenia V.
Virovets, Alexander V.
Kremer, Werner
Scheer, Manfred
Giant Rugby Ball [{Cp(Bn)Fe(η(5)-P(5))}(24)Cu(96)Br(96)] Derived from Pentaphosphaferrocene and CuBr(2)
title Giant Rugby Ball [{Cp(Bn)Fe(η(5)-P(5))}(24)Cu(96)Br(96)] Derived from Pentaphosphaferrocene and CuBr(2)
title_full Giant Rugby Ball [{Cp(Bn)Fe(η(5)-P(5))}(24)Cu(96)Br(96)] Derived from Pentaphosphaferrocene and CuBr(2)
title_fullStr Giant Rugby Ball [{Cp(Bn)Fe(η(5)-P(5))}(24)Cu(96)Br(96)] Derived from Pentaphosphaferrocene and CuBr(2)
title_full_unstemmed Giant Rugby Ball [{Cp(Bn)Fe(η(5)-P(5))}(24)Cu(96)Br(96)] Derived from Pentaphosphaferrocene and CuBr(2)
title_short Giant Rugby Ball [{Cp(Bn)Fe(η(5)-P(5))}(24)Cu(96)Br(96)] Derived from Pentaphosphaferrocene and CuBr(2)
title_sort giant rugby ball [{cp(bn)fe(η(5)-p(5))}(24)cu(96)br(96)] derived from pentaphosphaferrocene and cubr(2)
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4593573/
https://www.ncbi.nlm.nih.gov/pubmed/26280785
http://dx.doi.org/10.1021/jacs.5b06835
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