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Homolytic N–H Activation of Ammonia: Hydrogen Transfer of Parent Iridium Ammine, Amide, Imide, and Nitride Species
[Image: see text] The redox series [Ir(n)(NH(x))(PNP)] (n = II–IV, x = 3–0; PNP = N(CHCHPtBu(2))(2)) was examined with respect to electron, proton, and hydrogen atom transfer steps. The experimental and computational results suggest that the Ir(III) imido species [Ir(NH)(PNP)] is not stable but unde...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American
Chemical Society
2015
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4597254/ https://www.ncbi.nlm.nih.gov/pubmed/26192601 http://dx.doi.org/10.1021/acs.inorgchem.5b00829 |