Spectroscopic and Crystal Field Consequences of Fluoride Binding by [Yb⋅DTMA](3+) in Aqueous Solution

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Yb⋅DTMA forms a ternary complex with fluoride in aqueous solution by displacement of a bound solvent molecule from the lanthanide ion. [Yb⋅DTMA⋅F](2+) and [Yb⋅DTMA⋅OH(2)](3+) are in slow exchange on the relevant NMR timescale (<2000 s(−1)), and profound differences are observed in their respectiv...

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Detalles Bibliográficos
Autores principales: Blackburn, Octavia A, Chilton, Nicholas F, Keller, Katharina, Tait, Claudia E, Myers, William K, McInnes, Eric J L, Kenwright, Alan M, Beer, Paul D, Timmel, Christiane R, Faulkner, Stephen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2015
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4611957/
https://www.ncbi.nlm.nih.gov/pubmed/26223970
http://dx.doi.org/10.1002/anie.201503421
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