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Synthesis, Characterization, and Reactivity of Functionalized Trinuclear Iron–Sulfur Clusters – A New Class of Bioinspired Hydrogenase Models

The air- and moisture-stable iron–sulfur carbonyl clusters Fe(3)S(2)(CO)(7)(dppm) (1) and Fe(3)S(2)(CO)(7)(dppf) (2) carrying the bisphosphine ligands bis(diphenylphosphanyl)methane (dppm) and 1,1′-bis(diphenylphosphanyl)ferrocene (dppf) were prepared and fully characterized. Two alternative synthet...

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Detalles Bibliográficos
Autores principales:	Kaiser, Manuel, Knör, Günther
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	WILEY-VCH Verlag 2015
Materias:	Full Papers
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4612652/ https://www.ncbi.nlm.nih.gov/pubmed/26512211 http://dx.doi.org/10.1002/ejic.201500574

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