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Mini-ISES identifies promising carbafructopyranose-based salens for asymmetric catalysis: Tuning ligand shape via the anomeric effect

This study introduces new methods of screening for and tuning chiral space and in so doing identifies a promising set of chiral ligands for asymmetric synthesis. The carbafructopyranosyl-1,2-diamine(s) and salens constructed therefrom are particularly compelling. It is shown that by removing the nat...

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Detalles Bibliográficos
Autores principales: Karukurichi, Kannan R., Fei, Xiang, Swyka, Robert A., Broussy, Sylvain, Shen, Weijun, Dey, Sangeeta, Roy, Sandip K., Berkowitz, David B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Association for the Advancement of Science 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4613784/
https://www.ncbi.nlm.nih.gov/pubmed/26501130
http://dx.doi.org/10.1126/sciadv.1500066