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The Reductive Activation of CO(2) Across a Ti=Ti Double Bond: Synthetic, Structural, and Mechanistic Studies

[Image: see text] The reactivity of the bis(pentalene)dititanium double-sandwich compound Ti(2)Pn(†)(2) (1) (Pn(†) = 1,4-{Si(i)Pr(3)}(2)C(8)H(4)) with CO(2) is investigated in detail using spectroscopic, X-ray crystallographic, and computational studies. When the CO(2) reaction is performed at −78 °...

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Detalles Bibliográficos
Autores principales:	Kilpatrick, Alexander F. R., Green, Jennifer C., Cloke, F. Geoffrey N.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2015
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4623487/ https://www.ncbi.nlm.nih.gov/pubmed/26538790 http://dx.doi.org/10.1021/acs.organomet.5b00315

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