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Accelerated CO(2) transport on surface of AgO nanoparticles in ionic liquid BMIMBF(4)

The AgO nanoparticles were utilized for a CO(2) separation membrane. The AgO nanoparticles were successfully generated in ionic liquid 1-butyl-3-methyl imidazolium tetrafluoroborate (BMIMBF(4)) by favorable interaction between the surface of particles and the counteranion of BMIMBF(4). The generated...

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Detalles Bibliográficos
Autores principales: Ji, Dahye, Kang, Yong Soo, Kang, Sang Wook
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4637840/
https://www.ncbi.nlm.nih.gov/pubmed/26549605
http://dx.doi.org/10.1038/srep16362
Descripción
Sumario:The AgO nanoparticles were utilized for a CO(2) separation membrane. The AgO nanoparticles were successfully generated in ionic liquid 1-butyl-3-methyl imidazolium tetrafluoroborate (BMIMBF(4)) by favorable interaction between the surface of particles and the counteranion of BMIMBF(4). The generated AgO nanoparticles were confirmed by TEM, and the average size was 20 nm. Coordinative interactions of dissociated AgO particles with BMIM(+)BF(4)(−) were investigated by FT-Raman spectroscopy. When the ionic liquid BMIMBF(4) containing AgO nanoparticles was utilized as a CO(2) separation membrane, the separation performance was largely enhanced.