Microwave-Assisted Syntheses in Recyclable Ionic Liquids: Photoresists Based on Renewable Resources

The copoly(2-oxazoline) pNonOx(80)-stat-pDc(=)Ox(20) can be synthesized from the cationic ring-opening copolymerization of 2-nonyl-2-oxazoline NonOx and 2-dec-9′-enyl-2-oxazoline Dc(=)Ox in the ionic liquid n-hexyl methylimidazolium tetrafluoroborate under microwave irradiation in 250 g/batch quanti...

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Autores principales: Petit, Charlotte, Luef, Klaus P, Edler, Matthias, Griesser, Thomas, Kremsner, Jennifer M, Stadler, Alexander, Grassl, Bruno, Reynaud, Stéphanie, Wiesbrock, Frank
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Blackwell Publishing Ltd 2015
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4641455/
https://www.ncbi.nlm.nih.gov/pubmed/26354027
http://dx.doi.org/10.1002/cssc.201500847
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author Petit, Charlotte
Luef, Klaus P
Edler, Matthias
Griesser, Thomas
Kremsner, Jennifer M
Stadler, Alexander
Grassl, Bruno
Reynaud, Stéphanie
Wiesbrock, Frank
author_facet Petit, Charlotte
Luef, Klaus P
Edler, Matthias
Griesser, Thomas
Kremsner, Jennifer M
Stadler, Alexander
Grassl, Bruno
Reynaud, Stéphanie
Wiesbrock, Frank
author_sort Petit, Charlotte
collection PubMed
description The copoly(2-oxazoline) pNonOx(80)-stat-pDc(=)Ox(20) can be synthesized from the cationic ring-opening copolymerization of 2-nonyl-2-oxazoline NonOx and 2-dec-9′-enyl-2-oxazoline Dc(=)Ox in the ionic liquid n-hexyl methylimidazolium tetrafluoroborate under microwave irradiation in 250 g/batch quantities. The polymer precipitates upon cooling, enabling easy recovery of the polymer and the ionic liquid. Both monomers can be obtained from fatty acids from renewable resources. pNonOx(80)-stat-pDc(=)Ox(20) can be used as polymer in a photoresist (resolution of 1 μm) based on UV-induced thiol–ene reactions.
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spelling pubmed-46414552015-11-16 Microwave-Assisted Syntheses in Recyclable Ionic Liquids: Photoresists Based on Renewable Resources Petit, Charlotte Luef, Klaus P Edler, Matthias Griesser, Thomas Kremsner, Jennifer M Stadler, Alexander Grassl, Bruno Reynaud, Stéphanie Wiesbrock, Frank ChemSusChem Communications The copoly(2-oxazoline) pNonOx(80)-stat-pDc(=)Ox(20) can be synthesized from the cationic ring-opening copolymerization of 2-nonyl-2-oxazoline NonOx and 2-dec-9′-enyl-2-oxazoline Dc(=)Ox in the ionic liquid n-hexyl methylimidazolium tetrafluoroborate under microwave irradiation in 250 g/batch quantities. The polymer precipitates upon cooling, enabling easy recovery of the polymer and the ionic liquid. Both monomers can be obtained from fatty acids from renewable resources. pNonOx(80)-stat-pDc(=)Ox(20) can be used as polymer in a photoresist (resolution of 1 μm) based on UV-induced thiol–ene reactions. Blackwell Publishing Ltd 2015-10 2015-09-10 /pmc/articles/PMC4641455/ /pubmed/26354027 http://dx.doi.org/10.1002/cssc.201500847 Text en © 2015 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. http://creativecommons.org/licenses/by/4.0/ This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Communications
Petit, Charlotte
Luef, Klaus P
Edler, Matthias
Griesser, Thomas
Kremsner, Jennifer M
Stadler, Alexander
Grassl, Bruno
Reynaud, Stéphanie
Wiesbrock, Frank
Microwave-Assisted Syntheses in Recyclable Ionic Liquids: Photoresists Based on Renewable Resources
title Microwave-Assisted Syntheses in Recyclable Ionic Liquids: Photoresists Based on Renewable Resources
title_full Microwave-Assisted Syntheses in Recyclable Ionic Liquids: Photoresists Based on Renewable Resources
title_fullStr Microwave-Assisted Syntheses in Recyclable Ionic Liquids: Photoresists Based on Renewable Resources
title_full_unstemmed Microwave-Assisted Syntheses in Recyclable Ionic Liquids: Photoresists Based on Renewable Resources
title_short Microwave-Assisted Syntheses in Recyclable Ionic Liquids: Photoresists Based on Renewable Resources
title_sort microwave-assisted syntheses in recyclable ionic liquids: photoresists based on renewable resources
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4641455/
https://www.ncbi.nlm.nih.gov/pubmed/26354027
http://dx.doi.org/10.1002/cssc.201500847
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