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Treatment of an automobile effluent from heavy metals contamination by an eco-friendly montmorillonite
Unmodified montmorillonite clay was utilized as a low cost adsorbent for the removal of heavy metals from a contaminated automobile effluent. Fourier transform infrared spectroscopy, X-ray diffraction and scanning electron microscopy were used to characterize the adsorbent. Batch sorption experiment...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Elsevier
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4642158/ https://www.ncbi.nlm.nih.gov/pubmed/26644939 http://dx.doi.org/10.1016/j.jare.2014.12.004 |
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author | Akpomie, Kovo G. Dawodu, Folasegun A. |
author_facet | Akpomie, Kovo G. Dawodu, Folasegun A. |
author_sort | Akpomie, Kovo G. |
collection | PubMed |
description | Unmodified montmorillonite clay was utilized as a low cost adsorbent for the removal of heavy metals from a contaminated automobile effluent. Fourier transform infrared spectroscopy, X-ray diffraction and scanning electron microscopy were used to characterize the adsorbent. Batch sorption experiments were performed at an optimum effluent pH of 6.5, adsorbent dose of 0.1 g, particle size of 100 μm and equilibrium contact time of 180 min. Thermodynamic analysis was also conducted. Equilibrium data were analyzed by the Langmuir, Freundlich, Temkin and Dubinin–Radushkevich models. A heterogeneous surface of the adsorbent was indicated by the Freundlich model. The Langmuir maximum adsorption capacity of the montmorillonite for metals was found in the following order: Zn (5.7 mg/g) > Cu (1.58 mg/g) > Mn (0.59 mg/g) > Cd (0.33 mg/g) > Pb (0.10 mg/g) ≡ Ni (0.10 mg/g). This was directly related to the concentration of the metal ions in solution. The pseudo-first order, pseudo-second order, intraparticle diffusion and liquid film diffusion models were applied for kinetic analysis. The mechanism of sorption was found to be dominated by the film diffusion mechanism. The results of this study revealed the potential of the montmorillonite for treatment of heavy metal contaminated effluents. |
format | Online Article Text |
id | pubmed-4642158 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | Elsevier |
record_format | MEDLINE/PubMed |
spelling | pubmed-46421582015-12-07 Treatment of an automobile effluent from heavy metals contamination by an eco-friendly montmorillonite Akpomie, Kovo G. Dawodu, Folasegun A. J Adv Res Original Article Unmodified montmorillonite clay was utilized as a low cost adsorbent for the removal of heavy metals from a contaminated automobile effluent. Fourier transform infrared spectroscopy, X-ray diffraction and scanning electron microscopy were used to characterize the adsorbent. Batch sorption experiments were performed at an optimum effluent pH of 6.5, adsorbent dose of 0.1 g, particle size of 100 μm and equilibrium contact time of 180 min. Thermodynamic analysis was also conducted. Equilibrium data were analyzed by the Langmuir, Freundlich, Temkin and Dubinin–Radushkevich models. A heterogeneous surface of the adsorbent was indicated by the Freundlich model. The Langmuir maximum adsorption capacity of the montmorillonite for metals was found in the following order: Zn (5.7 mg/g) > Cu (1.58 mg/g) > Mn (0.59 mg/g) > Cd (0.33 mg/g) > Pb (0.10 mg/g) ≡ Ni (0.10 mg/g). This was directly related to the concentration of the metal ions in solution. The pseudo-first order, pseudo-second order, intraparticle diffusion and liquid film diffusion models were applied for kinetic analysis. The mechanism of sorption was found to be dominated by the film diffusion mechanism. The results of this study revealed the potential of the montmorillonite for treatment of heavy metal contaminated effluents. Elsevier 2015-11 2014-12-19 /pmc/articles/PMC4642158/ /pubmed/26644939 http://dx.doi.org/10.1016/j.jare.2014.12.004 Text en © 2014 Production and hosting by Elsevier B.V. on behalf of Cairo University. http://creativecommons.org/licenses/by-nc-nd/4.0/ This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/). |
spellingShingle | Original Article Akpomie, Kovo G. Dawodu, Folasegun A. Treatment of an automobile effluent from heavy metals contamination by an eco-friendly montmorillonite |
title | Treatment of an automobile effluent from heavy metals contamination by an eco-friendly montmorillonite |
title_full | Treatment of an automobile effluent from heavy metals contamination by an eco-friendly montmorillonite |
title_fullStr | Treatment of an automobile effluent from heavy metals contamination by an eco-friendly montmorillonite |
title_full_unstemmed | Treatment of an automobile effluent from heavy metals contamination by an eco-friendly montmorillonite |
title_short | Treatment of an automobile effluent from heavy metals contamination by an eco-friendly montmorillonite |
title_sort | treatment of an automobile effluent from heavy metals contamination by an eco-friendly montmorillonite |
topic | Original Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4642158/ https://www.ncbi.nlm.nih.gov/pubmed/26644939 http://dx.doi.org/10.1016/j.jare.2014.12.004 |
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