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Observation of the simplest Criegee intermediate CH(2)OO in the gas-phase ozonolysis of ethylene

Ozonolysis is one of the dominant oxidation pathways for tropospheric alkenes. Although numerous studies have confirmed a 1,3-cycloaddition mechanism that generates a Criegee intermediate (CI) with form R(1)R(2)COO, no small CIs have ever been directly observed in the ozonolysis of alkenes because o...

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Detalles Bibliográficos
Autores principales:	Womack, Caroline C., Martin-Drumel, Marie-Aline, Brown, Gordon G., Field, Robert W., McCarthy, Michael C.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Association for the Advancement of Science 2015
Materias:	Research Articles
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4643816/ https://www.ncbi.nlm.nih.gov/pubmed/26601145 http://dx.doi.org/10.1126/sciadv.1400105

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