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Crystal structure of (E)-2-amino-4-methylsulfanyl-6-oxo-1-{[(thiophen-2-yl)methylidene]amino}-1,6-dihydropyrimidine-5-carbonitrile
The title compound, C(11)H(9)N(5)OS(2), a 1-thiophen-2-ylmethyleneaminopyrimidine derivative, displays an essentially planar C—NH(2) group. The conformation across the N=C bond linking the pyrimidine and thienyl groups is E. The pyrimidine and thienyl ring systems subtend an inter-planar angle...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4644996/ https://www.ncbi.nlm.nih.gov/pubmed/26594500 http://dx.doi.org/10.1107/S205698901501885X |
Sumario: | The title compound, C(11)H(9)N(5)OS(2), a 1-thiophen-2-ylmethyleneaminopyrimidine derivative, displays an essentially planar C—NH(2) group. The conformation across the N=C bond linking the pyrimidine and thienyl groups is E. The pyrimidine and thienyl ring systems subtend an inter-planar angle of 42.72 (5)°. In the crystal, molecules are linked by N–H⋯N(nitrile) and N–H⋯O=C hydrogen bonds, forming chains parallel to the b axis. |
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