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Crystal structure of (2E,4E)-5-[bis(2-hydroxyethyl)amino]-1-(4-chlorophenyl)-5-phenylpenta-2,4-dien-1-one
In the title compound, C(21)H(22)ClNO(3), the pentadiene unit is nearly planar [maximum deviation = 0.023 (1) Å], but the carbonyl O atom deviates significantly [by 0.304 (1) Å] from its mean plane, which is twisted with respect to the phenyl and chlorobenzene rings by 71.34 (13) and 46.40 (13)°,...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4645000/ https://www.ncbi.nlm.nih.gov/pubmed/26594571 http://dx.doi.org/10.1107/S2056989015019568 |
Sumario: | In the title compound, C(21)H(22)ClNO(3), the pentadiene unit is nearly planar [maximum deviation = 0.023 (1) Å], but the carbonyl O atom deviates significantly [by 0.304 (1) Å] from its mean plane, which is twisted with respect to the phenyl and chlorobenzene rings by 71.34 (13) and 46.40 (13)°, respectively. In the crystal, inversion-related molecules are linked by two pairs of O—H⋯O hydrogen bonds, forming chains propagating along [01-1], enclosing R (2) (2)(16) and R (2) (2)(22) ring motifs. The chains are linked via C—H⋯O hydrogen bonds and C—H⋯π interactions into a three-dimensional supramolecular architecture. |
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