Crystal structure of an organic–inorganic hybrid compound based on morpholinium cations and a β-type Anderson polyanion

A new organic–inorganic hybrid compound, penta­morpholinium hexa­hydrogen hexa­molybdoferrate(III) sulfate 3.5-hydrate, (C(4)H(10)NO)(5)[Fe(III)(OH)(6)Mo(6)O(18)](SO(4))·3.5H(2)O, was obtained from an aqueous solution. The polyoxidomolybdate (POM) anion is of the Anderson β-type with a central Fe(II...

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Detalles Bibliográficos
Autores principales: Lukianova, Tamara J., Kinzhybalo, Vasyl, Pietraszko, Adam
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4645003/
https://www.ncbi.nlm.nih.gov/pubmed/26594507
http://dx.doi.org/10.1107/S2056989015019246
Descripción
Sumario:A new organic–inorganic hybrid compound, penta­morpholinium hexa­hydrogen hexa­molybdoferrate(III) sulfate 3.5-hydrate, (C(4)H(10)NO)(5)[Fe(III)(OH)(6)Mo(6)O(18)](SO(4))·3.5H(2)O, was obtained from an aqueous solution. The polyoxidomolybdate (POM) anion is of the Anderson β-type with a central Fe(III) ion. Three of five crystallographically independent morpholinium cations are disordered over two sets of sites. An intricate network of inter­molecular N—H⋯O and O—H⋯O inter­actions between cations, POMs, sulfate anions and non-coordinating water mol­ecules creates a three-dimensional network structure.

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