Crystal structure of an organic–inorganic hybrid compound based on morpholinium cations and a β-type Anderson polyanion

A new organic–inorganic hybrid compound, penta­morpholinium hexa­hydrogen hexa­molybdoferrate(III) sulfate 3.5-hydrate, (C(4)H(10)NO)(5)[Fe(III)(OH)(6)Mo(6)O(18)](SO(4))·3.5H(2)O, was obtained from an aqueous solution. The polyoxidomolybdate (POM) anion is of the Anderson β-type with a central Fe(II...

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Autores principales: Lukianova, Tamara J., Kinzhybalo, Vasyl, Pietraszko, Adam
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4645003/
https://www.ncbi.nlm.nih.gov/pubmed/26594507
http://dx.doi.org/10.1107/S2056989015019246
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author Lukianova, Tamara J.
Kinzhybalo, Vasyl
Pietraszko, Adam
author_facet Lukianova, Tamara J.
Kinzhybalo, Vasyl
Pietraszko, Adam
author_sort Lukianova, Tamara J.
collection PubMed
description A new organic–inorganic hybrid compound, penta­morpholinium hexa­hydrogen hexa­molybdoferrate(III) sulfate 3.5-hydrate, (C(4)H(10)NO)(5)[Fe(III)(OH)(6)Mo(6)O(18)](SO(4))·3.5H(2)O, was obtained from an aqueous solution. The polyoxidomolybdate (POM) anion is of the Anderson β-type with a central Fe(III) ion. Three of five crystallographically independent morpholinium cations are disordered over two sets of sites. An intricate network of inter­molecular N—H⋯O and O—H⋯O inter­actions between cations, POMs, sulfate anions and non-coordinating water mol­ecules creates a three-dimensional network structure.
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spelling pubmed-46450032015-11-20 Crystal structure of an organic–inorganic hybrid compound based on morpholinium cations and a β-type Anderson polyanion Lukianova, Tamara J. Kinzhybalo, Vasyl Pietraszko, Adam Acta Crystallogr E Crystallogr Commun Research Communications A new organic–inorganic hybrid compound, penta­morpholinium hexa­hydrogen hexa­molybdoferrate(III) sulfate 3.5-hydrate, (C(4)H(10)NO)(5)[Fe(III)(OH)(6)Mo(6)O(18)](SO(4))·3.5H(2)O, was obtained from an aqueous solution. The polyoxidomolybdate (POM) anion is of the Anderson β-type with a central Fe(III) ion. Three of five crystallographically independent morpholinium cations are disordered over two sets of sites. An intricate network of inter­molecular N—H⋯O and O—H⋯O inter­actions between cations, POMs, sulfate anions and non-coordinating water mol­ecules creates a three-dimensional network structure. International Union of Crystallography 2015-10-17 /pmc/articles/PMC4645003/ /pubmed/26594507 http://dx.doi.org/10.1107/S2056989015019246 Text en © Lukianova et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Lukianova, Tamara J.
Kinzhybalo, Vasyl
Pietraszko, Adam
Crystal structure of an organic–inorganic hybrid compound based on morpholinium cations and a β-type Anderson polyanion
title Crystal structure of an organic–inorganic hybrid compound based on morpholinium cations and a β-type Anderson polyanion
title_full Crystal structure of an organic–inorganic hybrid compound based on morpholinium cations and a β-type Anderson polyanion
title_fullStr Crystal structure of an organic–inorganic hybrid compound based on morpholinium cations and a β-type Anderson polyanion
title_full_unstemmed Crystal structure of an organic–inorganic hybrid compound based on morpholinium cations and a β-type Anderson polyanion
title_short Crystal structure of an organic–inorganic hybrid compound based on morpholinium cations and a β-type Anderson polyanion
title_sort crystal structure of an organic–inorganic hybrid compound based on morpholinium cations and a β-type anderson polyanion
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4645003/
https://www.ncbi.nlm.nih.gov/pubmed/26594507
http://dx.doi.org/10.1107/S2056989015019246
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AT pietraszkoadam crystalstructureofanorganicinorganichybridcompoundbasedonmorpholiniumcationsandabtypeandersonpolyanion

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