Crystal structure of di-μ-iodido-bis­[bis(aceto­nitrile-κN)copper(I)]

The title compound, [Cu(2)I(2)(CH(3)CN)(4)], exhibits a centrosymmetric Cu(2)I(2) core [Cu⋯Cu distance = 2.7482 (11) Å], the Cu(I) atoms of which are further coordinated by four mol­ecules of aceto­nitrile. The Cu(I) atom has an overall distorted tetra­hedral coordination environment evidenced by L—...

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Detalles Bibliográficos
Autores principales: Barth, Eva Rebecca, Golz, Christopher, Knorr, Michael, Strohmann, Carsten
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4645014/
https://www.ncbi.nlm.nih.gov/pubmed/26594527
http://dx.doi.org/10.1107/S2056989015018149
Descripción
Sumario:The title compound, [Cu(2)I(2)(CH(3)CN)(4)], exhibits a centrosymmetric Cu(2)I(2) core [Cu⋯Cu distance = 2.7482 (11) Å], the Cu(I) atoms of which are further coordinated by four mol­ecules of aceto­nitrile. The Cu(I) atom has an overall distorted tetra­hedral coordination environment evidenced by L—Cu—L angles (L = N or I) ranging from 100.47 (10) to 117.06 (2)°. The coordination geometries of the aceto­nitrile ligands deviate slightly from linearity as shown by Cu—N—C angles of 167.0 (2) and 172.7 (2)°. In the crystal, there are no significant hydrogen-bonding inter­actions present, so the crystal packing seems to be formed predominantly by van der Waals forces.

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