Crystal structure of 2-bromo-4,6-di­nitroaniline

In the title compound, C(6)H(4)BrN(3)O(4), the dihedral angles between the nitro groups and the aniline ring are 2.04 (3) and 1.18 (4)°, respectively. In the crystal, N—H⋯O and C—H⋯O hydrogen bonds and weak side-on C—Br⋯π inter­actions [3.5024 (12) Å] link adjacent mol­ecules, forming a three-dimens...

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Autores principales: Kang, Gihaeng, Kim, Tae Ho, Lee, Eui-Jae, Kang, Chang Ho
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4645020/
https://www.ncbi.nlm.nih.gov/pubmed/26594540
http://dx.doi.org/10.1107/S2056989015017946
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author Kang, Gihaeng
Kim, Tae Ho
Lee, Eui-Jae
Kang, Chang Ho
author_facet Kang, Gihaeng
Kim, Tae Ho
Lee, Eui-Jae
Kang, Chang Ho
author_sort Kang, Gihaeng
collection PubMed
description In the title compound, C(6)H(4)BrN(3)O(4), the dihedral angles between the nitro groups and the aniline ring are 2.04 (3) and 1.18 (4)°, respectively. In the crystal, N—H⋯O and C—H⋯O hydrogen bonds and weak side-on C—Br⋯π inter­actions [3.5024 (12) Å] link adjacent mol­ecules, forming a three-dimensional network. A close O⋯Br contact [3.259 (2) Å] may also add additional stability.
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spelling pubmed-46450202015-11-20 Crystal structure of 2-bromo-4,6-di­nitroaniline Kang, Gihaeng Kim, Tae Ho Lee, Eui-Jae Kang, Chang Ho Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, C(6)H(4)BrN(3)O(4), the dihedral angles between the nitro groups and the aniline ring are 2.04 (3) and 1.18 (4)°, respectively. In the crystal, N—H⋯O and C—H⋯O hydrogen bonds and weak side-on C—Br⋯π inter­actions [3.5024 (12) Å] link adjacent mol­ecules, forming a three-dimensional network. A close O⋯Br contact [3.259 (2) Å] may also add additional stability. International Union of Crystallography 2015-10-03 /pmc/articles/PMC4645020/ /pubmed/26594540 http://dx.doi.org/10.1107/S2056989015017946 Text en © Kang et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Kang, Gihaeng
Kim, Tae Ho
Lee, Eui-Jae
Kang, Chang Ho
Crystal structure of 2-bromo-4,6-di­nitroaniline
title Crystal structure of 2-bromo-4,6-di­nitroaniline
title_full Crystal structure of 2-bromo-4,6-di­nitroaniline
title_fullStr Crystal structure of 2-bromo-4,6-di­nitroaniline
title_full_unstemmed Crystal structure of 2-bromo-4,6-di­nitroaniline
title_short Crystal structure of 2-bromo-4,6-di­nitroaniline
title_sort crystal structure of 2-bromo-4,6-di­nitroaniline
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4645020/
https://www.ncbi.nlm.nih.gov/pubmed/26594540
http://dx.doi.org/10.1107/S2056989015017946
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