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Crystal structure of 3-meth­oxy-2-[5-(naphthalen-1-yl)-4,5-di­hydro-1H-pyrazol-3-yl]phenol

In the title compound, C(20)H(18)N(2)O(2), the central pyrazoline ring has an envelope conformation with the atom substituted by the naphthalene ring as the flap. It bridges a benzene ring and a naphthalene ring system which are almost normal to one another, making a dihedral angle of 82.03 (6) °. T...

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Autor principal: Koh, Dongsoo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4645021/
https://www.ncbi.nlm.nih.gov/pubmed/26594549
http://dx.doi.org/10.1107/S2056989015018472
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author Koh, Dongsoo
author_facet Koh, Dongsoo
author_sort Koh, Dongsoo
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description In the title compound, C(20)H(18)N(2)O(2), the central pyrazoline ring has an envelope conformation with the atom substituted by the naphthalene ring as the flap. It bridges a benzene ring and a naphthalene ring system which are almost normal to one another, making a dihedral angle of 82.03 (6) °. There is an intra­molecular O—H⋯N hydrogen bond forming an S(6) ring motif. In the crystal, mol­ecules are linked by pairs of N—H⋯π inter­actions, forming inversion dimers. There are also C—H⋯π inter­actions present and the dimers are linked via C—H⋯O hydrogen bonds, forming ribbons propagating along the a-axis direction.
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spelling pubmed-46450212015-11-20 Crystal structure of 3-meth­oxy-2-[5-(naphthalen-1-yl)-4,5-di­hydro-1H-pyrazol-3-yl]phenol Koh, Dongsoo Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, C(20)H(18)N(2)O(2), the central pyrazoline ring has an envelope conformation with the atom substituted by the naphthalene ring as the flap. It bridges a benzene ring and a naphthalene ring system which are almost normal to one another, making a dihedral angle of 82.03 (6) °. There is an intra­molecular O—H⋯N hydrogen bond forming an S(6) ring motif. In the crystal, mol­ecules are linked by pairs of N—H⋯π inter­actions, forming inversion dimers. There are also C—H⋯π inter­actions present and the dimers are linked via C—H⋯O hydrogen bonds, forming ribbons propagating along the a-axis direction. International Union of Crystallography 2015-10-07 /pmc/articles/PMC4645021/ /pubmed/26594549 http://dx.doi.org/10.1107/S2056989015018472 Text en © Dongsoo Koh 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Koh, Dongsoo
Crystal structure of 3-meth­oxy-2-[5-(naphthalen-1-yl)-4,5-di­hydro-1H-pyrazol-3-yl]phenol
title Crystal structure of 3-meth­oxy-2-[5-(naphthalen-1-yl)-4,5-di­hydro-1H-pyrazol-3-yl]phenol
title_full Crystal structure of 3-meth­oxy-2-[5-(naphthalen-1-yl)-4,5-di­hydro-1H-pyrazol-3-yl]phenol
title_fullStr Crystal structure of 3-meth­oxy-2-[5-(naphthalen-1-yl)-4,5-di­hydro-1H-pyrazol-3-yl]phenol
title_full_unstemmed Crystal structure of 3-meth­oxy-2-[5-(naphthalen-1-yl)-4,5-di­hydro-1H-pyrazol-3-yl]phenol
title_short Crystal structure of 3-meth­oxy-2-[5-(naphthalen-1-yl)-4,5-di­hydro-1H-pyrazol-3-yl]phenol
title_sort crystal structure of 3-meth­oxy-2-[5-(naphthalen-1-yl)-4,5-di­hydro-1h-pyrazol-3-yl]phenol
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4645021/
https://www.ncbi.nlm.nih.gov/pubmed/26594549
http://dx.doi.org/10.1107/S2056989015018472
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