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Crystal structure of 3-methoxy-2-[5-(naphthalen-1-yl)-4,5-dihydro-1H-pyrazol-3-yl]phenol
In the title compound, C(20)H(18)N(2)O(2), the central pyrazoline ring has an envelope conformation with the atom substituted by the naphthalene ring as the flap. It bridges a benzene ring and a naphthalene ring system which are almost normal to one another, making a dihedral angle of 82.03 (6) °. T...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2015
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4645021/ https://www.ncbi.nlm.nih.gov/pubmed/26594549 http://dx.doi.org/10.1107/S2056989015018472 |
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author | Koh, Dongsoo |
author_facet | Koh, Dongsoo |
author_sort | Koh, Dongsoo |
collection | PubMed |
description | In the title compound, C(20)H(18)N(2)O(2), the central pyrazoline ring has an envelope conformation with the atom substituted by the naphthalene ring as the flap. It bridges a benzene ring and a naphthalene ring system which are almost normal to one another, making a dihedral angle of 82.03 (6) °. There is an intramolecular O—H⋯N hydrogen bond forming an S(6) ring motif. In the crystal, molecules are linked by pairs of N—H⋯π interactions, forming inversion dimers. There are also C—H⋯π interactions present and the dimers are linked via C—H⋯O hydrogen bonds, forming ribbons propagating along the a-axis direction. |
format | Online Article Text |
id | pubmed-4645021 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-46450212015-11-20 Crystal structure of 3-methoxy-2-[5-(naphthalen-1-yl)-4,5-dihydro-1H-pyrazol-3-yl]phenol Koh, Dongsoo Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, C(20)H(18)N(2)O(2), the central pyrazoline ring has an envelope conformation with the atom substituted by the naphthalene ring as the flap. It bridges a benzene ring and a naphthalene ring system which are almost normal to one another, making a dihedral angle of 82.03 (6) °. There is an intramolecular O—H⋯N hydrogen bond forming an S(6) ring motif. In the crystal, molecules are linked by pairs of N—H⋯π interactions, forming inversion dimers. There are also C—H⋯π interactions present and the dimers are linked via C—H⋯O hydrogen bonds, forming ribbons propagating along the a-axis direction. International Union of Crystallography 2015-10-07 /pmc/articles/PMC4645021/ /pubmed/26594549 http://dx.doi.org/10.1107/S2056989015018472 Text en © Dongsoo Koh 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Koh, Dongsoo Crystal structure of 3-methoxy-2-[5-(naphthalen-1-yl)-4,5-dihydro-1H-pyrazol-3-yl]phenol |
title | Crystal structure of 3-methoxy-2-[5-(naphthalen-1-yl)-4,5-dihydro-1H-pyrazol-3-yl]phenol |
title_full | Crystal structure of 3-methoxy-2-[5-(naphthalen-1-yl)-4,5-dihydro-1H-pyrazol-3-yl]phenol |
title_fullStr | Crystal structure of 3-methoxy-2-[5-(naphthalen-1-yl)-4,5-dihydro-1H-pyrazol-3-yl]phenol |
title_full_unstemmed | Crystal structure of 3-methoxy-2-[5-(naphthalen-1-yl)-4,5-dihydro-1H-pyrazol-3-yl]phenol |
title_short | Crystal structure of 3-methoxy-2-[5-(naphthalen-1-yl)-4,5-dihydro-1H-pyrazol-3-yl]phenol |
title_sort | crystal structure of 3-methoxy-2-[5-(naphthalen-1-yl)-4,5-dihydro-1h-pyrazol-3-yl]phenol |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4645021/ https://www.ncbi.nlm.nih.gov/pubmed/26594549 http://dx.doi.org/10.1107/S2056989015018472 |
work_keys_str_mv | AT kohdongsoo crystalstructureof3methoxy25naphthalen1yl45dihydro1hpyrazol3ylphenol |