Crystal structure of [butane-2,3-dione bis­(4-methyl­thio­semicarbazonato)-κ(4) S,N (1),N (1′),S′](pyridine-κN)zinc(II)

In the structure of the title complex, [Zn(C(8)H(14)N(6)S(2))(C(5)H(5)N)], the Zn(II) ion has a pseudo-square-pyramidal coordination environment and is displaced by 0.490 Å from the plane of best fit defined by the bis­(thio­semicarbazonate) N(2)S(2) donor atoms. Chains sustained by intermolecular N...

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Detalles Bibliográficos
Autores principales: Brown, Oliver C., Tocher, Derek A., Blower, Philip J., Went, Michael J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4645023/
https://www.ncbi.nlm.nih.gov/pubmed/26594508
http://dx.doi.org/10.1107/S2056989015019234
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author Brown, Oliver C.
Tocher, Derek A.
Blower, Philip J.
Went, Michael J.
author_facet Brown, Oliver C.
Tocher, Derek A.
Blower, Philip J.
Went, Michael J.
author_sort Brown, Oliver C.
collection PubMed
description In the structure of the title complex, [Zn(C(8)H(14)N(6)S(2))(C(5)H(5)N)], the Zn(II) ion has a pseudo-square-pyramidal coordination environment and is displaced by 0.490 Å from the plane of best fit defined by the bis­(thio­semicarbazonate) N(2)S(2) donor atoms. Chains sustained by intermolecular N—H⋯N and N—H⋯S hydrogen-bonding interactions extend parallel to [10-1].
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spelling pubmed-46450232015-11-20 Crystal structure of [butane-2,3-dione bis­(4-methyl­thio­semicarbazonato)-κ(4) S,N (1),N (1′),S′](pyridine-κN)zinc(II) Brown, Oliver C. Tocher, Derek A. Blower, Philip J. Went, Michael J. Acta Crystallogr E Crystallogr Commun Research Communications In the structure of the title complex, [Zn(C(8)H(14)N(6)S(2))(C(5)H(5)N)], the Zn(II) ion has a pseudo-square-pyramidal coordination environment and is displaced by 0.490 Å from the plane of best fit defined by the bis­(thio­semicarbazonate) N(2)S(2) donor atoms. Chains sustained by intermolecular N—H⋯N and N—H⋯S hydrogen-bonding interactions extend parallel to [10-1]. International Union of Crystallography 2015-10-17 /pmc/articles/PMC4645023/ /pubmed/26594508 http://dx.doi.org/10.1107/S2056989015019234 Text en © Brown et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Brown, Oliver C.
Tocher, Derek A.
Blower, Philip J.
Went, Michael J.
Crystal structure of [butane-2,3-dione bis­(4-methyl­thio­semicarbazonato)-κ(4) S,N (1),N (1′),S′](pyridine-κN)zinc(II)
title Crystal structure of [butane-2,3-dione bis­(4-methyl­thio­semicarbazonato)-κ(4) S,N (1),N (1′),S′](pyridine-κN)zinc(II)
title_full Crystal structure of [butane-2,3-dione bis­(4-methyl­thio­semicarbazonato)-κ(4) S,N (1),N (1′),S′](pyridine-κN)zinc(II)
title_fullStr Crystal structure of [butane-2,3-dione bis­(4-methyl­thio­semicarbazonato)-κ(4) S,N (1),N (1′),S′](pyridine-κN)zinc(II)
title_full_unstemmed Crystal structure of [butane-2,3-dione bis­(4-methyl­thio­semicarbazonato)-κ(4) S,N (1),N (1′),S′](pyridine-κN)zinc(II)
title_short Crystal structure of [butane-2,3-dione bis­(4-methyl­thio­semicarbazonato)-κ(4) S,N (1),N (1′),S′](pyridine-κN)zinc(II)
title_sort crystal structure of [butane-2,3-dione bis­(4-methyl­thio­semicarbazonato)-κ(4) s,n (1),n (1′),s′](pyridine-κn)zinc(ii)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4645023/
https://www.ncbi.nlm.nih.gov/pubmed/26594508
http://dx.doi.org/10.1107/S2056989015019234
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