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Crystal structure of 1-methyl-2-methylamino-3-nitro-1H-chromeno[2,3-b]pyridin-5(10aH)-one
In the title compound, C(14)H(13)N(3)O(4), the pyran ring adopts an envelope conformation with the methine C atom as the flap. The dihedral angle between the benzene and hydropyridine rings is 29.33 (3)°. The methylamine C atom deviates from the plane of its attached ring by 0.380 (5) Å and an int...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4645028/ https://www.ncbi.nlm.nih.gov/pubmed/26594547 http://dx.doi.org/10.1107/S2056989015018241 |
Sumario: | In the title compound, C(14)H(13)N(3)O(4), the pyran ring adopts an envelope conformation with the methine C atom as the flap. The dihedral angle between the benzene and hydropyridine rings is 29.33 (3)°. The methylamine C atom deviates from the plane of its attached ring by 0.380 (5) Å and an intramolecular N—H⋯O hydrogen bond closes an S(6) ring. In the crystal, weak C—H⋯O hydrogen bonds and aromatic π–π stacking interactions [centroid–centroid distances vary from 3.6529 (10) to 3.6872 (10) Å] link the molecules, generating a three-dimensional network. |
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