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Crystal structure of (E)-1-(2,4-dinitrophenyl)-2-[(E)-5-phenyl-1-(p-tolyl)pent-2-en-4-yn-1-ylidene]hydrazine
In the title compound, C(24)H(18)N(4)O(4), the plane of the phenyl ring is inclined to those of the toluene ring and the dinitro-substituted benzene ring by 66.96 (19) and 47.06 (18)°, respectively, while the planes of the two benzene rings are inclined to one another by 36.26 (19)°. There is an in...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4645032/ https://www.ncbi.nlm.nih.gov/pubmed/26594558 http://dx.doi.org/10.1107/S2056989015019301 |
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author | Golovanov, Alexander A. Vologzhanina, Anna V. Voronova, Evgeniya D. Bekin, Vadim V. Naumov, Sergey V. |
author_facet | Golovanov, Alexander A. Vologzhanina, Anna V. Voronova, Evgeniya D. Bekin, Vadim V. Naumov, Sergey V. |
author_sort | Golovanov, Alexander A. |
collection | PubMed |
description | In the title compound, C(24)H(18)N(4)O(4), the plane of the phenyl ring is inclined to those of the toluene ring and the dinitro-substituted benzene ring by 66.96 (19) and 47.06 (18)°, respectively, while the planes of the two benzene rings are inclined to one another by 36.26 (19)°. There is an intramolecular N—H⋯O hydrogen bond between the NH group and the O atom of a nitro group, forming an S(6) ring motif. In the crystal, molecules are linked by C—H⋯O hydrogen bonds and C—H⋯π interactions, forming a three-dimensional network. There are also weak π–π interactions present involving the phenyl ring and the dinitro-substituted benzene ring [inter-centroid distance = 3.741 (2) Å]. |
format | Online Article Text |
id | pubmed-4645032 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-46450322015-11-20 Crystal structure of (E)-1-(2,4-dinitrophenyl)-2-[(E)-5-phenyl-1-(p-tolyl)pent-2-en-4-yn-1-ylidene]hydrazine Golovanov, Alexander A. Vologzhanina, Anna V. Voronova, Evgeniya D. Bekin, Vadim V. Naumov, Sergey V. Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, C(24)H(18)N(4)O(4), the plane of the phenyl ring is inclined to those of the toluene ring and the dinitro-substituted benzene ring by 66.96 (19) and 47.06 (18)°, respectively, while the planes of the two benzene rings are inclined to one another by 36.26 (19)°. There is an intramolecular N—H⋯O hydrogen bond between the NH group and the O atom of a nitro group, forming an S(6) ring motif. In the crystal, molecules are linked by C—H⋯O hydrogen bonds and C—H⋯π interactions, forming a three-dimensional network. There are also weak π–π interactions present involving the phenyl ring and the dinitro-substituted benzene ring [inter-centroid distance = 3.741 (2) Å]. International Union of Crystallography 2015-10-17 /pmc/articles/PMC4645032/ /pubmed/26594558 http://dx.doi.org/10.1107/S2056989015019301 Text en © Golovanov et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Golovanov, Alexander A. Vologzhanina, Anna V. Voronova, Evgeniya D. Bekin, Vadim V. Naumov, Sergey V. Crystal structure of (E)-1-(2,4-dinitrophenyl)-2-[(E)-5-phenyl-1-(p-tolyl)pent-2-en-4-yn-1-ylidene]hydrazine |
title | Crystal structure of (E)-1-(2,4-dinitrophenyl)-2-[(E)-5-phenyl-1-(p-tolyl)pent-2-en-4-yn-1-ylidene]hydrazine |
title_full | Crystal structure of (E)-1-(2,4-dinitrophenyl)-2-[(E)-5-phenyl-1-(p-tolyl)pent-2-en-4-yn-1-ylidene]hydrazine |
title_fullStr | Crystal structure of (E)-1-(2,4-dinitrophenyl)-2-[(E)-5-phenyl-1-(p-tolyl)pent-2-en-4-yn-1-ylidene]hydrazine |
title_full_unstemmed | Crystal structure of (E)-1-(2,4-dinitrophenyl)-2-[(E)-5-phenyl-1-(p-tolyl)pent-2-en-4-yn-1-ylidene]hydrazine |
title_short | Crystal structure of (E)-1-(2,4-dinitrophenyl)-2-[(E)-5-phenyl-1-(p-tolyl)pent-2-en-4-yn-1-ylidene]hydrazine |
title_sort | crystal structure of (e)-1-(2,4-dinitrophenyl)-2-[(e)-5-phenyl-1-(p-tolyl)pent-2-en-4-yn-1-ylidene]hydrazine |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4645032/ https://www.ncbi.nlm.nih.gov/pubmed/26594558 http://dx.doi.org/10.1107/S2056989015019301 |
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