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Crystal structure of (E)-1-(2,4-di­nitro­phen­yl)-2-[(E)-5-phenyl-1-(p-tol­yl)pent-2-en-4-yn-1-yl­idene]hydrazine

In the title compound, C(24)H(18)N(4)O(4), the plane of the phenyl ring is inclined to those of the toluene ring and the di­nitro-substituted benzene ring by 66.96 (19) and 47.06 (18)°, respectively, while the planes of the two benzene rings are inclined to one another by 36.26 (19)°. There is an in...

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Autores principales: Golovanov, Alexander A., Vologzhanina, Anna V., Voronova, Evgeniya D., Bekin, Vadim V., Naumov, Sergey V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4645032/
https://www.ncbi.nlm.nih.gov/pubmed/26594558
http://dx.doi.org/10.1107/S2056989015019301
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author Golovanov, Alexander A.
Vologzhanina, Anna V.
Voronova, Evgeniya D.
Bekin, Vadim V.
Naumov, Sergey V.
author_facet Golovanov, Alexander A.
Vologzhanina, Anna V.
Voronova, Evgeniya D.
Bekin, Vadim V.
Naumov, Sergey V.
author_sort Golovanov, Alexander A.
collection PubMed
description In the title compound, C(24)H(18)N(4)O(4), the plane of the phenyl ring is inclined to those of the toluene ring and the di­nitro-substituted benzene ring by 66.96 (19) and 47.06 (18)°, respectively, while the planes of the two benzene rings are inclined to one another by 36.26 (19)°. There is an intra­molecular N—H⋯O hydrogen bond between the NH group and the O atom of a nitro group, forming an S(6) ring motif. In the crystal, mol­ecules are linked by C—H⋯O hydrogen bonds and C—H⋯π inter­actions, forming a three-dimensional network. There are also weak π–π inter­actions present involving the phenyl ring and the di­nitro-substituted benzene ring [inter-centroid distance = 3.741 (2) Å].
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spelling pubmed-46450322015-11-20 Crystal structure of (E)-1-(2,4-di­nitro­phen­yl)-2-[(E)-5-phenyl-1-(p-tol­yl)pent-2-en-4-yn-1-yl­idene]hydrazine Golovanov, Alexander A. Vologzhanina, Anna V. Voronova, Evgeniya D. Bekin, Vadim V. Naumov, Sergey V. Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, C(24)H(18)N(4)O(4), the plane of the phenyl ring is inclined to those of the toluene ring and the di­nitro-substituted benzene ring by 66.96 (19) and 47.06 (18)°, respectively, while the planes of the two benzene rings are inclined to one another by 36.26 (19)°. There is an intra­molecular N—H⋯O hydrogen bond between the NH group and the O atom of a nitro group, forming an S(6) ring motif. In the crystal, mol­ecules are linked by C—H⋯O hydrogen bonds and C—H⋯π inter­actions, forming a three-dimensional network. There are also weak π–π inter­actions present involving the phenyl ring and the di­nitro-substituted benzene ring [inter-centroid distance = 3.741 (2) Å]. International Union of Crystallography 2015-10-17 /pmc/articles/PMC4645032/ /pubmed/26594558 http://dx.doi.org/10.1107/S2056989015019301 Text en © Golovanov et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Golovanov, Alexander A.
Vologzhanina, Anna V.
Voronova, Evgeniya D.
Bekin, Vadim V.
Naumov, Sergey V.
Crystal structure of (E)-1-(2,4-di­nitro­phen­yl)-2-[(E)-5-phenyl-1-(p-tol­yl)pent-2-en-4-yn-1-yl­idene]hydrazine
title Crystal structure of (E)-1-(2,4-di­nitro­phen­yl)-2-[(E)-5-phenyl-1-(p-tol­yl)pent-2-en-4-yn-1-yl­idene]hydrazine
title_full Crystal structure of (E)-1-(2,4-di­nitro­phen­yl)-2-[(E)-5-phenyl-1-(p-tol­yl)pent-2-en-4-yn-1-yl­idene]hydrazine
title_fullStr Crystal structure of (E)-1-(2,4-di­nitro­phen­yl)-2-[(E)-5-phenyl-1-(p-tol­yl)pent-2-en-4-yn-1-yl­idene]hydrazine
title_full_unstemmed Crystal structure of (E)-1-(2,4-di­nitro­phen­yl)-2-[(E)-5-phenyl-1-(p-tol­yl)pent-2-en-4-yn-1-yl­idene]hydrazine
title_short Crystal structure of (E)-1-(2,4-di­nitro­phen­yl)-2-[(E)-5-phenyl-1-(p-tol­yl)pent-2-en-4-yn-1-yl­idene]hydrazine
title_sort crystal structure of (e)-1-(2,4-di­nitro­phen­yl)-2-[(e)-5-phenyl-1-(p-tol­yl)pent-2-en-4-yn-1-yl­idene]hydrazine
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4645032/
https://www.ncbi.nlm.nih.gov/pubmed/26594558
http://dx.doi.org/10.1107/S2056989015019301
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