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Crystal structure of N-(2-amino-5-cyano-4-methylsulfanyl-6-oxo-1,6-dihydropyrimidin-1-yl)-4-bromobenzenesulfonamide dimethylformamide monosolvate
The title compound, C(12)H(10)BrN(5)O(3)S(2)·C(3)H(7)NO, displays an almost planar amine group. The interplanar angle between the rings is 31.72 (6)°. The residues are associated into ribbons parallel to [110] by three classical hydrogen bonds; one from each amine H(amine) to O(DMF) and one from NH...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4645039/ https://www.ncbi.nlm.nih.gov/pubmed/26594501 http://dx.doi.org/10.1107/S2056989015018903 |
Sumario: | The title compound, C(12)H(10)BrN(5)O(3)S(2)·C(3)H(7)NO, displays an almost planar amine group. The interplanar angle between the rings is 31.72 (6)°. The residues are associated into ribbons parallel to [110] by three classical hydrogen bonds; one from each amine H(amine) to O(DMF) and one from NH(amide) to O(oxo). Adjacent ribbons are connected by translation parallel to the c axis by a ‘weak’ hydrogen bond H(methyl)⋯O(sulfonyl) to form a layer structure parallel to (1-10), while a further contact H(bromophenyl)⋯O(sulfonyl) connects the residues in the third dimension. |
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