Crystal structure of N-(2-amino-5-cyano-4-methyl­sulfanyl-6-oxo-1,6-dihydropyrimidin-1-yl)-4-bromo­benzene­sulfonamide di­methyl­formamide monosolvate

The title compound, C(12)H(10)BrN(5)O(3)S(2)·C(3)H(7)NO, displays an almost planar amine group. The inter­planar angle between the rings is 31.72 (6)°. The residues are associated into ribbons parallel to [110] by three classical hydrogen bonds; one from each amine H(amine) to O(DMF) and one from NH...

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Autores principales: Elgemeie, Galal H., Mohamed, Reham A., Hussein, Hoda A., Jones, Peter G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4645039/
https://www.ncbi.nlm.nih.gov/pubmed/26594501
http://dx.doi.org/10.1107/S2056989015018903
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author Elgemeie, Galal H.
Mohamed, Reham A.
Hussein, Hoda A.
Jones, Peter G.
author_facet Elgemeie, Galal H.
Mohamed, Reham A.
Hussein, Hoda A.
Jones, Peter G.
author_sort Elgemeie, Galal H.
collection PubMed
description The title compound, C(12)H(10)BrN(5)O(3)S(2)·C(3)H(7)NO, displays an almost planar amine group. The inter­planar angle between the rings is 31.72 (6)°. The residues are associated into ribbons parallel to [110] by three classical hydrogen bonds; one from each amine H(amine) to O(DMF) and one from NH(amide) to O(oxo). Adjacent ribbons are connected by translation parallel to the c axis by a ‘weak’ hydrogen bond H(meth­yl)⋯O(sulfon­yl) to form a layer structure parallel to (1-10), while a further contact H(bromo­phen­yl)⋯O(sulfon­yl) connects the residues in the third dimension.
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spelling pubmed-46450392015-11-20 Crystal structure of N-(2-amino-5-cyano-4-methyl­sulfanyl-6-oxo-1,6-dihydropyrimidin-1-yl)-4-bromo­benzene­sulfonamide di­methyl­formamide monosolvate Elgemeie, Galal H. Mohamed, Reham A. Hussein, Hoda A. Jones, Peter G. Acta Crystallogr E Crystallogr Commun Research Communications The title compound, C(12)H(10)BrN(5)O(3)S(2)·C(3)H(7)NO, displays an almost planar amine group. The inter­planar angle between the rings is 31.72 (6)°. The residues are associated into ribbons parallel to [110] by three classical hydrogen bonds; one from each amine H(amine) to O(DMF) and one from NH(amide) to O(oxo). Adjacent ribbons are connected by translation parallel to the c axis by a ‘weak’ hydrogen bond H(meth­yl)⋯O(sulfon­yl) to form a layer structure parallel to (1-10), while a further contact H(bromo­phen­yl)⋯O(sulfon­yl) connects the residues in the third dimension. International Union of Crystallography 2015-10-14 /pmc/articles/PMC4645039/ /pubmed/26594501 http://dx.doi.org/10.1107/S2056989015018903 Text en © Elgemeie et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Elgemeie, Galal H.
Mohamed, Reham A.
Hussein, Hoda A.
Jones, Peter G.
Crystal structure of N-(2-amino-5-cyano-4-methyl­sulfanyl-6-oxo-1,6-dihydropyrimidin-1-yl)-4-bromo­benzene­sulfonamide di­methyl­formamide monosolvate
title Crystal structure of N-(2-amino-5-cyano-4-methyl­sulfanyl-6-oxo-1,6-dihydropyrimidin-1-yl)-4-bromo­benzene­sulfonamide di­methyl­formamide monosolvate
title_full Crystal structure of N-(2-amino-5-cyano-4-methyl­sulfanyl-6-oxo-1,6-dihydropyrimidin-1-yl)-4-bromo­benzene­sulfonamide di­methyl­formamide monosolvate
title_fullStr Crystal structure of N-(2-amino-5-cyano-4-methyl­sulfanyl-6-oxo-1,6-dihydropyrimidin-1-yl)-4-bromo­benzene­sulfonamide di­methyl­formamide monosolvate
title_full_unstemmed Crystal structure of N-(2-amino-5-cyano-4-methyl­sulfanyl-6-oxo-1,6-dihydropyrimidin-1-yl)-4-bromo­benzene­sulfonamide di­methyl­formamide monosolvate
title_short Crystal structure of N-(2-amino-5-cyano-4-methyl­sulfanyl-6-oxo-1,6-dihydropyrimidin-1-yl)-4-bromo­benzene­sulfonamide di­methyl­formamide monosolvate
title_sort crystal structure of n-(2-amino-5-cyano-4-methyl­sulfanyl-6-oxo-1,6-dihydropyrimidin-1-yl)-4-bromo­benzene­sulfonamide di­methyl­formamide monosolvate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4645039/
https://www.ncbi.nlm.nih.gov/pubmed/26594501
http://dx.doi.org/10.1107/S2056989015018903
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