Crystal structure of [μ(2)-3,3-dimethyl-4-(propan-2-yl­idene)thietane-2,2-dithiol­ato-κ(4) S:S′:S:S′]bis[tricarbonyl­iron(I)](Fe—Fe)

The title complex, [Fe(2)(C(8)H(12)S(3))(CO)(6)] or [{Fe(CO)(3)}(2)(μ-L)] [L = 3,3-dimethyl-4-(propan-2-yl­idene)thietane-2,2-bis­(thiol­ato)], consists of two Fe(CO)(3) moieties double-bridged by a di­thiol­ate ligand. Each of the two Fe(I) atoms has a distorted anti-prismatic coordination environm...

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Detalles Bibliográficos
Autores principales: Zhao, Peihua, Bertke, Jeffery A., Rauchfuss, Thomas B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4645041/
https://www.ncbi.nlm.nih.gov/pubmed/26594495
http://dx.doi.org/10.1107/S2056989015018496
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author Zhao, Peihua
Bertke, Jeffery A.
Rauchfuss, Thomas B.
author_facet Zhao, Peihua
Bertke, Jeffery A.
Rauchfuss, Thomas B.
author_sort Zhao, Peihua
collection PubMed
description The title complex, [Fe(2)(C(8)H(12)S(3))(CO)(6)] or [{Fe(CO)(3)}(2)(μ-L)] [L = 3,3-dimethyl-4-(propan-2-yl­idene)thietane-2,2-bis­(thiol­ato)], consists of two Fe(CO)(3) moieties double-bridged by a di­thiol­ate ligand. Each of the two Fe(I) atoms has a distorted anti-prismatic coordination environment consisting of three carbonyl groups, two S atoms of the di­thiol­ate ligand and the neighboring Fe(I) atom [Fe—Fe = 2.4921 (4) Å]. Weak C—H⋯O inter­molecular inter­actions result in the formation of dimers. This is the second crystal structure reported with the 3,3-dimethyl-4-(propan-2-yl­idene)thietane-2,2-bis­(thiol­ate) ligand and the first in which it bridges two metal atoms.
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spelling pubmed-46450412015-11-20 Crystal structure of [μ(2)-3,3-dimethyl-4-(propan-2-yl­idene)thietane-2,2-dithiol­ato-κ(4) S:S′:S:S′]bis[tricarbonyl­iron(I)](Fe—Fe) Zhao, Peihua Bertke, Jeffery A. Rauchfuss, Thomas B. Acta Crystallogr E Crystallogr Commun Research Communications The title complex, [Fe(2)(C(8)H(12)S(3))(CO)(6)] or [{Fe(CO)(3)}(2)(μ-L)] [L = 3,3-dimethyl-4-(propan-2-yl­idene)thietane-2,2-bis­(thiol­ato)], consists of two Fe(CO)(3) moieties double-bridged by a di­thiol­ate ligand. Each of the two Fe(I) atoms has a distorted anti-prismatic coordination environment consisting of three carbonyl groups, two S atoms of the di­thiol­ate ligand and the neighboring Fe(I) atom [Fe—Fe = 2.4921 (4) Å]. Weak C—H⋯O inter­molecular inter­actions result in the formation of dimers. This is the second crystal structure reported with the 3,3-dimethyl-4-(propan-2-yl­idene)thietane-2,2-bis­(thiol­ate) ligand and the first in which it bridges two metal atoms. International Union of Crystallography 2015-10-10 /pmc/articles/PMC4645041/ /pubmed/26594495 http://dx.doi.org/10.1107/S2056989015018496 Text en © Zhao et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Zhao, Peihua
Bertke, Jeffery A.
Rauchfuss, Thomas B.
Crystal structure of [μ(2)-3,3-dimethyl-4-(propan-2-yl­idene)thietane-2,2-dithiol­ato-κ(4) S:S′:S:S′]bis[tricarbonyl­iron(I)](Fe—Fe)
title Crystal structure of [μ(2)-3,3-dimethyl-4-(propan-2-yl­idene)thietane-2,2-dithiol­ato-κ(4) S:S′:S:S′]bis[tricarbonyl­iron(I)](Fe—Fe)
title_full Crystal structure of [μ(2)-3,3-dimethyl-4-(propan-2-yl­idene)thietane-2,2-dithiol­ato-κ(4) S:S′:S:S′]bis[tricarbonyl­iron(I)](Fe—Fe)
title_fullStr Crystal structure of [μ(2)-3,3-dimethyl-4-(propan-2-yl­idene)thietane-2,2-dithiol­ato-κ(4) S:S′:S:S′]bis[tricarbonyl­iron(I)](Fe—Fe)
title_full_unstemmed Crystal structure of [μ(2)-3,3-dimethyl-4-(propan-2-yl­idene)thietane-2,2-dithiol­ato-κ(4) S:S′:S:S′]bis[tricarbonyl­iron(I)](Fe—Fe)
title_short Crystal structure of [μ(2)-3,3-dimethyl-4-(propan-2-yl­idene)thietane-2,2-dithiol­ato-κ(4) S:S′:S:S′]bis[tricarbonyl­iron(I)](Fe—Fe)
title_sort crystal structure of [μ(2)-3,3-dimethyl-4-(propan-2-yl­idene)thietane-2,2-dithiol­ato-κ(4) s:s′:s:s′]bis[tricarbonyl­iron(i)](fe—fe)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4645041/
https://www.ncbi.nlm.nih.gov/pubmed/26594495
http://dx.doi.org/10.1107/S2056989015018496
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