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Crystal structure of [μ(2)-3,3-dimethyl-4-(propan-2-ylidene)thietane-2,2-dithiolato-κ(4) S:S′:S:S′]bis[tricarbonyliron(I)](Fe—Fe)
The title complex, [Fe(2)(C(8)H(12)S(3))(CO)(6)] or [{Fe(CO)(3)}(2)(μ-L)] [L = 3,3-dimethyl-4-(propan-2-ylidene)thietane-2,2-bis(thiolato)], consists of two Fe(CO)(3) moieties double-bridged by a dithiolate ligand. Each of the two Fe(I) atoms has a distorted anti-prismatic coordination environm...
Autores principales: | Zhao, Peihua, Bertke, Jeffery A., Rauchfuss, Thomas B. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4645041/ https://www.ncbi.nlm.nih.gov/pubmed/26594495 http://dx.doi.org/10.1107/S2056989015018496 |
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