Crystal structure of 1,2,3,5-di-O-methyl­ene-α-d-xylo­furan­ose

The title compound, C(7)H(10)O(5), was synthesized by reaction of d-xylose with paraformaldehyde. In the crystal, the central part of the mol­ecule consists of a five-membered C(4)O ring with an envelope conformation, with the methine C atom adjacent to the O atom being the flap. The protected O ato...

Descripción completa

Detalles Bibliográficos
Autores principales: Tiritiris, Ioannis, Tussetschläger, Stefan, Kantlehner, Willi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4645044/
https://www.ncbi.nlm.nih.gov/pubmed/26594582
http://dx.doi.org/10.1107/S2056989015020022
_version_ 1782400749241630720
author Tiritiris, Ioannis
Tussetschläger, Stefan
Kantlehner, Willi
author_facet Tiritiris, Ioannis
Tussetschläger, Stefan
Kantlehner, Willi
author_sort Tiritiris, Ioannis
collection PubMed
description The title compound, C(7)H(10)O(5), was synthesized by reaction of d-xylose with paraformaldehyde. In the crystal, the central part of the mol­ecule consists of a five-membered C(4)O ring with an envelope conformation, with the methine C atom adjacent to the O atom being the flap. The protected O atoms of both cyclic acetal groups are oriented so that the four chiral C atoms of the furan­ose part show an R configuration. C—H⋯O hydrogen bonds are present between adjacent mol­ecules, generating a three-dimensional network.
format Online
Article
Text
id pubmed-4645044
institution National Center for Biotechnology Information
language English
publishDate 2015
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-46450442015-11-20 Crystal structure of 1,2,3,5-di-O-methyl­ene-α-d-xylo­furan­ose Tiritiris, Ioannis Tussetschläger, Stefan Kantlehner, Willi Acta Crystallogr E Crystallogr Commun Data Reports The title compound, C(7)H(10)O(5), was synthesized by reaction of d-xylose with paraformaldehyde. In the crystal, the central part of the mol­ecule consists of a five-membered C(4)O ring with an envelope conformation, with the methine C atom adjacent to the O atom being the flap. The protected O atoms of both cyclic acetal groups are oriented so that the four chiral C atoms of the furan­ose part show an R configuration. C—H⋯O hydrogen bonds are present between adjacent mol­ecules, generating a three-dimensional network. International Union of Crystallography 2015-10-28 /pmc/articles/PMC4645044/ /pubmed/26594582 http://dx.doi.org/10.1107/S2056989015020022 Text en © Tiritiris et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Tiritiris, Ioannis
Tussetschläger, Stefan
Kantlehner, Willi
Crystal structure of 1,2,3,5-di-O-methyl­ene-α-d-xylo­furan­ose
title Crystal structure of 1,2,3,5-di-O-methyl­ene-α-d-xylo­furan­ose
title_full Crystal structure of 1,2,3,5-di-O-methyl­ene-α-d-xylo­furan­ose
title_fullStr Crystal structure of 1,2,3,5-di-O-methyl­ene-α-d-xylo­furan­ose
title_full_unstemmed Crystal structure of 1,2,3,5-di-O-methyl­ene-α-d-xylo­furan­ose
title_short Crystal structure of 1,2,3,5-di-O-methyl­ene-α-d-xylo­furan­ose
title_sort crystal structure of 1,2,3,5-di-o-methyl­ene-α-d-xylo­furan­ose
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4645044/
https://www.ncbi.nlm.nih.gov/pubmed/26594582
http://dx.doi.org/10.1107/S2056989015020022
work_keys_str_mv AT tiritirisioannis crystalstructureof1235diomethyleneadxylofuranose
AT tussetschlagerstefan crystalstructureof1235diomethyleneadxylofuranose
AT kantlehnerwilli crystalstructureof1235diomethyleneadxylofuranose

Ejemplares similares