Crystal structure of new organically templated copper sulfate with 2-amino­pyridinium

The title compound, (C(5)H(7)N(2))(2)[Cu(H(2)O)(6)](SO(4))(2)·4H(2)O [systematic name: bis(2-aminopyridinium) hexaaquacopper(II) bis(sulfate) tetrahydrate], comprises axially elongated hexa­aqua-coordinated octa­hedral Cu(II) ions located on an inversion centre, non-coordinating sulfate anions, 2-am...

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Autores principales: Lukianova, Tamara J., Kinzhybalo, Vasyl, Pietraszko, Adam
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4645056/
https://www.ncbi.nlm.nih.gov/pubmed/26594528
http://dx.doi.org/10.1107/S2056989015018629
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author Lukianova, Tamara J.
Kinzhybalo, Vasyl
Pietraszko, Adam
author_facet Lukianova, Tamara J.
Kinzhybalo, Vasyl
Pietraszko, Adam
author_sort Lukianova, Tamara J.
collection PubMed
description The title compound, (C(5)H(7)N(2))(2)[Cu(H(2)O)(6)](SO(4))(2)·4H(2)O [systematic name: bis(2-aminopyridinium) hexaaquacopper(II) bis(sulfate) tetrahydrate], comprises axially elongated hexa­aqua-coordinated octa­hedral Cu(II) ions located on an inversion centre, non-coordinating sulfate anions, 2-amino­pyridinium cations and lattice water mol­ecules. The crystal structure is built of successive inorganic and organic layers extending parallel to (001) that are connected by an extensive three-dimensional hydrogen-bonded network of the type O—H⋯O and N—H⋯O, as well as π–π inter­actions [centroid–centroid distance 3.4140 (14) Å, offset 0.277 Å].
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spelling pubmed-46450562015-11-20 Crystal structure of new organically templated copper sulfate with 2-amino­pyridinium Lukianova, Tamara J. Kinzhybalo, Vasyl Pietraszko, Adam Acta Crystallogr E Crystallogr Commun Data Reports The title compound, (C(5)H(7)N(2))(2)[Cu(H(2)O)(6)](SO(4))(2)·4H(2)O [systematic name: bis(2-aminopyridinium) hexaaquacopper(II) bis(sulfate) tetrahydrate], comprises axially elongated hexa­aqua-coordinated octa­hedral Cu(II) ions located on an inversion centre, non-coordinating sulfate anions, 2-amino­pyridinium cations and lattice water mol­ecules. The crystal structure is built of successive inorganic and organic layers extending parallel to (001) that are connected by an extensive three-dimensional hydrogen-bonded network of the type O—H⋯O and N—H⋯O, as well as π–π inter­actions [centroid–centroid distance 3.4140 (14) Å, offset 0.277 Å]. International Union of Crystallography 2015-10-10 /pmc/articles/PMC4645056/ /pubmed/26594528 http://dx.doi.org/10.1107/S2056989015018629 Text en © Lukianova et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Lukianova, Tamara J.
Kinzhybalo, Vasyl
Pietraszko, Adam
Crystal structure of new organically templated copper sulfate with 2-amino­pyridinium
title Crystal structure of new organically templated copper sulfate with 2-amino­pyridinium
title_full Crystal structure of new organically templated copper sulfate with 2-amino­pyridinium
title_fullStr Crystal structure of new organically templated copper sulfate with 2-amino­pyridinium
title_full_unstemmed Crystal structure of new organically templated copper sulfate with 2-amino­pyridinium
title_short Crystal structure of new organically templated copper sulfate with 2-amino­pyridinium
title_sort crystal structure of new organically templated copper sulfate with 2-amino­pyridinium
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4645056/
https://www.ncbi.nlm.nih.gov/pubmed/26594528
http://dx.doi.org/10.1107/S2056989015018629
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