Crystal structure of (Z)-2-benzyl­idene-4-methyl-2H-benzo[b][1,4]thia­zin-3(4H)-one

In the title compound, C(16)H(13)NOS, the 1,4-thia­zine ring displays a screw-boat conformation. The conformation about the ethene bond [1.344 (2) Å] is Z. The plane of the fused benzene ring makes a dihedral angle of 58.95 (9)° with the pendent phenyl ring, indicating a twisted conformation in the...

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Autores principales: Ellouz, Mohamed, Sebbar, Nada Kheira, Essassi, El Mokhtar, Saadi, Mohamed, El Ammari, Lahcen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4645059/
https://www.ncbi.nlm.nih.gov/pubmed/26594566
http://dx.doi.org/10.1107/S2056989015019295
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author Ellouz, Mohamed
Sebbar, Nada Kheira
Essassi, El Mokhtar
Saadi, Mohamed
El Ammari, Lahcen
author_facet Ellouz, Mohamed
Sebbar, Nada Kheira
Essassi, El Mokhtar
Saadi, Mohamed
El Ammari, Lahcen
author_sort Ellouz, Mohamed
collection PubMed
description In the title compound, C(16)H(13)NOS, the 1,4-thia­zine ring displays a screw-boat conformation. The conformation about the ethene bond [1.344 (2) Å] is Z. The plane of the fused benzene ring makes a dihedral angle of 58.95 (9)° with the pendent phenyl ring, indicating a twisted conformation in the mol­ecule. In the crystal, mol­ecules are linked by pairs of C—H⋯O hydrogen bonds, forming inversion dimers.
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spelling pubmed-46450592015-11-20 Crystal structure of (Z)-2-benzyl­idene-4-methyl-2H-benzo[b][1,4]thia­zin-3(4H)-one Ellouz, Mohamed Sebbar, Nada Kheira Essassi, El Mokhtar Saadi, Mohamed El Ammari, Lahcen Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, C(16)H(13)NOS, the 1,4-thia­zine ring displays a screw-boat conformation. The conformation about the ethene bond [1.344 (2) Å] is Z. The plane of the fused benzene ring makes a dihedral angle of 58.95 (9)° with the pendent phenyl ring, indicating a twisted conformation in the mol­ecule. In the crystal, mol­ecules are linked by pairs of C—H⋯O hydrogen bonds, forming inversion dimers. International Union of Crystallography 2015-10-17 /pmc/articles/PMC4645059/ /pubmed/26594566 http://dx.doi.org/10.1107/S2056989015019295 Text en © Ellouz et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Ellouz, Mohamed
Sebbar, Nada Kheira
Essassi, El Mokhtar
Saadi, Mohamed
El Ammari, Lahcen
Crystal structure of (Z)-2-benzyl­idene-4-methyl-2H-benzo[b][1,4]thia­zin-3(4H)-one
title Crystal structure of (Z)-2-benzyl­idene-4-methyl-2H-benzo[b][1,4]thia­zin-3(4H)-one
title_full Crystal structure of (Z)-2-benzyl­idene-4-methyl-2H-benzo[b][1,4]thia­zin-3(4H)-one
title_fullStr Crystal structure of (Z)-2-benzyl­idene-4-methyl-2H-benzo[b][1,4]thia­zin-3(4H)-one
title_full_unstemmed Crystal structure of (Z)-2-benzyl­idene-4-methyl-2H-benzo[b][1,4]thia­zin-3(4H)-one
title_short Crystal structure of (Z)-2-benzyl­idene-4-methyl-2H-benzo[b][1,4]thia­zin-3(4H)-one
title_sort crystal structure of (z)-2-benzyl­idene-4-methyl-2h-benzo[b][1,4]thia­zin-3(4h)-one
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4645059/
https://www.ncbi.nlm.nih.gov/pubmed/26594566
http://dx.doi.org/10.1107/S2056989015019295
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