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Crystal structure of {6,6′-dihydroxy-2,2′-[iminobis(propane-1,3-diylnitrilomethanylylidene)]diphenolato-κ(5) O (1),N,N′,N′′,O (1′)}copper(II)
The title compound, [Cu(C(20)H(23)N(3)O(4))], crystallizes in the space group Cc with two independent molecules in the asymmetric unit. The Cu(II) atoms are each coordinated by the pentadentate Schiff base ligand in a distorted trigonal bipyramidal N(3)O(2) geometry. The equatorial plane is formed...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2015
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4645064/ https://www.ncbi.nlm.nih.gov/pubmed/26594534 http://dx.doi.org/10.1107/S2056989015019684 |
| _version_ | 1782400753812373504 |
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| author | Noor, Shabana Kumar, Sarvendra Sabir, Suhail Seidel, Rüdiger W. Goddard, Richard |
| author_facet | Noor, Shabana Kumar, Sarvendra Sabir, Suhail Seidel, Rüdiger W. Goddard, Richard |
| author_sort | Noor, Shabana |
| collection | PubMed |
| description | The title compound, [Cu(C(20)H(23)N(3)O(4))], crystallizes in the space group Cc with two independent molecules in the asymmetric unit. The Cu(II) atoms are each coordinated by the pentadentate Schiff base ligand in a distorted trigonal bipyramidal N(3)O(2) geometry. The equatorial plane is formed by the two phenolic O atoms and the amine N atom, while the axial positions are occupied by the two imine N atoms. In the crystal, the two independent molecules are each connected into a column along the b axis through intermolecular O—H⋯O hydrogen bonds. The two independent columns are further linked through an N—H⋯O hydrogen bond, forming a double-column structure. |
| format | Online Article Text |
| id | pubmed-4645064 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2015 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-46450642015-11-20 Crystal structure of {6,6′-dihydroxy-2,2′-[iminobis(propane-1,3-diylnitrilomethanylylidene)]diphenolato-κ(5) O (1),N,N′,N′′,O (1′)}copper(II) Noor, Shabana Kumar, Sarvendra Sabir, Suhail Seidel, Rüdiger W. Goddard, Richard Acta Crystallogr E Crystallogr Commun Data Reports The title compound, [Cu(C(20)H(23)N(3)O(4))], crystallizes in the space group Cc with two independent molecules in the asymmetric unit. The Cu(II) atoms are each coordinated by the pentadentate Schiff base ligand in a distorted trigonal bipyramidal N(3)O(2) geometry. The equatorial plane is formed by the two phenolic O atoms and the amine N atom, while the axial positions are occupied by the two imine N atoms. In the crystal, the two independent molecules are each connected into a column along the b axis through intermolecular O—H⋯O hydrogen bonds. The two independent columns are further linked through an N—H⋯O hydrogen bond, forming a double-column structure. International Union of Crystallography 2015-10-24 /pmc/articles/PMC4645064/ /pubmed/26594534 http://dx.doi.org/10.1107/S2056989015019684 Text en © Noor et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Data Reports Noor, Shabana Kumar, Sarvendra Sabir, Suhail Seidel, Rüdiger W. Goddard, Richard Crystal structure of {6,6′-dihydroxy-2,2′-[iminobis(propane-1,3-diylnitrilomethanylylidene)]diphenolato-κ(5) O (1),N,N′,N′′,O (1′)}copper(II) |
| title | Crystal structure of {6,6′-dihydroxy-2,2′-[iminobis(propane-1,3-diylnitrilomethanylylidene)]diphenolato-κ(5)
O
(1),N,N′,N′′,O
(1′)}copper(II) |
| title_full | Crystal structure of {6,6′-dihydroxy-2,2′-[iminobis(propane-1,3-diylnitrilomethanylylidene)]diphenolato-κ(5)
O
(1),N,N′,N′′,O
(1′)}copper(II) |
| title_fullStr | Crystal structure of {6,6′-dihydroxy-2,2′-[iminobis(propane-1,3-diylnitrilomethanylylidene)]diphenolato-κ(5)
O
(1),N,N′,N′′,O
(1′)}copper(II) |
| title_full_unstemmed | Crystal structure of {6,6′-dihydroxy-2,2′-[iminobis(propane-1,3-diylnitrilomethanylylidene)]diphenolato-κ(5)
O
(1),N,N′,N′′,O
(1′)}copper(II) |
| title_short | Crystal structure of {6,6′-dihydroxy-2,2′-[iminobis(propane-1,3-diylnitrilomethanylylidene)]diphenolato-κ(5)
O
(1),N,N′,N′′,O
(1′)}copper(II) |
| title_sort | crystal structure of {6,6′-dihydroxy-2,2′-[iminobis(propane-1,3-diylnitrilomethanylylidene)]diphenolato-κ(5)
o
(1),n,n′,n′′,o
(1′)}copper(ii) |
| topic | Data Reports |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4645064/ https://www.ncbi.nlm.nih.gov/pubmed/26594534 http://dx.doi.org/10.1107/S2056989015019684 |
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