Synthesis and structural studies of a new complex of catena-poly[p-anisidinium [[diiodidobismu­thate(III)]-di-μ-iodido] dihydrate]

A new organic–inorganic hybrid material, {(C(7)H(10)NO)[BiI(4)]·2H(2)O}(n), has been synthesized by slow evaporation of an aqueous solution at room temperature. The anionic sublattice of the crystal is built up by [BiI(6)] octa­hedra sharing edges. The resulting zigzag chains extend along the a-axis...

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Detalles Bibliográficos
Autores principales: Touati, Mohamed El Mehdi, Elleuch, S., Boughzala, Habib
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4645070/
https://www.ncbi.nlm.nih.gov/pubmed/26594509
http://dx.doi.org/10.1107/S2056989015019489
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author Touati, Mohamed El Mehdi
Elleuch, S.
Boughzala, Habib
author_facet Touati, Mohamed El Mehdi
Elleuch, S.
Boughzala, Habib
author_sort Touati, Mohamed El Mehdi
collection PubMed
description A new organic–inorganic hybrid material, {(C(7)H(10)NO)[BiI(4)]·2H(2)O}(n), has been synthesized by slow evaporation of an aqueous solution at room temperature. The anionic sublattice of the crystal is built up by [BiI(6)] octa­hedra sharing edges. The resulting zigzag chains extend along the a-axis direction and are arranged in a distorted hexagonal rod packing. The p-anisidinium cations and the water mol­ecules are located in the voids of the anionic sublattice. The cations are linked to each other through N—H⋯O hydrogen bonds with the water mol­ecules, and also through weaker N—H⋯I inter­actions to the anionic inorganic layers.
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spelling pubmed-46450702015-11-20 Synthesis and structural studies of a new complex of catena-poly[p-anisidinium [[diiodidobismu­thate(III)]-di-μ-iodido] dihydrate] Touati, Mohamed El Mehdi Elleuch, S. Boughzala, Habib Acta Crystallogr E Crystallogr Commun Research Communications A new organic–inorganic hybrid material, {(C(7)H(10)NO)[BiI(4)]·2H(2)O}(n), has been synthesized by slow evaporation of an aqueous solution at room temperature. The anionic sublattice of the crystal is built up by [BiI(6)] octa­hedra sharing edges. The resulting zigzag chains extend along the a-axis direction and are arranged in a distorted hexagonal rod packing. The p-anisidinium cations and the water mol­ecules are located in the voids of the anionic sublattice. The cations are linked to each other through N—H⋯O hydrogen bonds with the water mol­ecules, and also through weaker N—H⋯I inter­actions to the anionic inorganic layers. International Union of Crystallography 2015-10-24 /pmc/articles/PMC4645070/ /pubmed/26594509 http://dx.doi.org/10.1107/S2056989015019489 Text en © Touati et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Touati, Mohamed El Mehdi
Elleuch, S.
Boughzala, Habib
Synthesis and structural studies of a new complex of catena-poly[p-anisidinium [[diiodidobismu­thate(III)]-di-μ-iodido] dihydrate]
title Synthesis and structural studies of a new complex of catena-poly[p-anisidinium [[diiodidobismu­thate(III)]-di-μ-iodido] dihydrate]
title_full Synthesis and structural studies of a new complex of catena-poly[p-anisidinium [[diiodidobismu­thate(III)]-di-μ-iodido] dihydrate]
title_fullStr Synthesis and structural studies of a new complex of catena-poly[p-anisidinium [[diiodidobismu­thate(III)]-di-μ-iodido] dihydrate]
title_full_unstemmed Synthesis and structural studies of a new complex of catena-poly[p-anisidinium [[diiodidobismu­thate(III)]-di-μ-iodido] dihydrate]
title_short Synthesis and structural studies of a new complex of catena-poly[p-anisidinium [[diiodidobismu­thate(III)]-di-μ-iodido] dihydrate]
title_sort synthesis and structural studies of a new complex of catena-poly[p-anisidinium [[diiodidobismu­thate(iii)]-di-μ-iodido] dihydrate]
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4645070/
https://www.ncbi.nlm.nih.gov/pubmed/26594509
http://dx.doi.org/10.1107/S2056989015019489
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AT boughzalahabib synthesisandstructuralstudiesofanewcomplexofcatenapolypanisidiniumdiiodidobismuthateiiidimiodidodihydrate

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