Crystal structure of 2-cyano-1-methyl­pyridinium perchlorate

The asymmetric unit of the title salt, C(7)H(7)N(2) (+)·ClO(4) (−), comprises two independent formula units. The solid-state structure comprises corrugated layers of cations and of anions, approximately parallel to (010). The supra­molecular layers are stabilized and connected by C—H⋯O hydrogen bond...

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Autores principales: Nguyen, Vu D., McCormick, Cameron A., Mague, Joel T., Koplitz, Lynn V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4645073/
https://www.ncbi.nlm.nih.gov/pubmed/26594561
http://dx.doi.org/10.1107/S2056989015019155
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author Nguyen, Vu D.
McCormick, Cameron A.
Mague, Joel T.
Koplitz, Lynn V.
author_facet Nguyen, Vu D.
McCormick, Cameron A.
Mague, Joel T.
Koplitz, Lynn V.
author_sort Nguyen, Vu D.
collection PubMed
description The asymmetric unit of the title salt, C(7)H(7)N(2) (+)·ClO(4) (−), comprises two independent formula units. The solid-state structure comprises corrugated layers of cations and of anions, approximately parallel to (010). The supra­molecular layers are stabilized and connected by C—H⋯O hydrogen bonding to consolidate a three-dimensional architecture. A close pyridin­ium–perchlorate N⋯O contact [2.867 (5) Å] is noted. The crystal was refined as an inversion twin.
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spelling pubmed-46450732015-11-20 Crystal structure of 2-cyano-1-methyl­pyridinium perchlorate Nguyen, Vu D. McCormick, Cameron A. Mague, Joel T. Koplitz, Lynn V. Acta Crystallogr E Crystallogr Commun Data Reports The asymmetric unit of the title salt, C(7)H(7)N(2) (+)·ClO(4) (−), comprises two independent formula units. The solid-state structure comprises corrugated layers of cations and of anions, approximately parallel to (010). The supra­molecular layers are stabilized and connected by C—H⋯O hydrogen bonding to consolidate a three-dimensional architecture. A close pyridin­ium–perchlorate N⋯O contact [2.867 (5) Å] is noted. The crystal was refined as an inversion twin. International Union of Crystallography 2015-10-17 /pmc/articles/PMC4645073/ /pubmed/26594561 http://dx.doi.org/10.1107/S2056989015019155 Text en © Nguyen et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Nguyen, Vu D.
McCormick, Cameron A.
Mague, Joel T.
Koplitz, Lynn V.
Crystal structure of 2-cyano-1-methyl­pyridinium perchlorate
title Crystal structure of 2-cyano-1-methyl­pyridinium perchlorate
title_full Crystal structure of 2-cyano-1-methyl­pyridinium perchlorate
title_fullStr Crystal structure of 2-cyano-1-methyl­pyridinium perchlorate
title_full_unstemmed Crystal structure of 2-cyano-1-methyl­pyridinium perchlorate
title_short Crystal structure of 2-cyano-1-methyl­pyridinium perchlorate
title_sort crystal structure of 2-cyano-1-methyl­pyridinium perchlorate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4645073/
https://www.ncbi.nlm.nih.gov/pubmed/26594561
http://dx.doi.org/10.1107/S2056989015019155
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