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Crystal structure of 5′′-(4-chloro­benzyl­idene)-4′-(4-chloro­phen­yl)-1′-methyltri­spiro[acenapthylene-1,2′-pyrrolidine-3′,1′′-cyclo­hexane-3′′,2′′′-[1,3]dioxane]-2(1H),6′′-dione

In the title compound, C(36)H(29)Cl(2)NO(4), two spiro links connect the methyl-substituted pyrrolidine ring to the ace­naphthyl­ene and cyclo­hexa­none rings. The cyclo­hexa­none ring is further connected to the dioxalane ring by a third spiro junction. The five-membered ring of the ace­naphthylen-...

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Autores principales: Chandralekha, Kuppan, Gavaskar, Deivasigamani, Sureshbabu, Adukamparai Rajukrishnan, Lakshmi, Srinivasakannan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4645075/
https://www.ncbi.nlm.nih.gov/pubmed/26594541
http://dx.doi.org/10.1107/S2056989015018034
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author Chandralekha, Kuppan
Gavaskar, Deivasigamani
Sureshbabu, Adukamparai Rajukrishnan
Lakshmi, Srinivasakannan
author_facet Chandralekha, Kuppan
Gavaskar, Deivasigamani
Sureshbabu, Adukamparai Rajukrishnan
Lakshmi, Srinivasakannan
author_sort Chandralekha, Kuppan
collection PubMed
description In the title compound, C(36)H(29)Cl(2)NO(4), two spiro links connect the methyl-substituted pyrrolidine ring to the ace­naphthyl­ene and cyclo­hexa­none rings. The cyclo­hexa­none ring is further connected to the dioxalane ring by a third spiro junction. The five-membered ring of the ace­naphthylen-1-one ring system adopts a flattened envelope conformation, with the ketonic C atom as the flap, whereas the dioxalane and pyrrolidine rings each have a twist conformation. The cyclo­hexenone ring assumes a boat conformation. An intra­molecular C—H⋯O hydrogen-bond inter­action is present. In the crystal, mol­ecules are linked by non-classical C—H⋯O hydrogen bonds, forming chains extending parallel to the a axis.
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spelling pubmed-46450752015-11-20 Crystal structure of 5′′-(4-chloro­benzyl­idene)-4′-(4-chloro­phen­yl)-1′-methyltri­spiro[acenapthylene-1,2′-pyrrolidine-3′,1′′-cyclo­hexane-3′′,2′′′-[1,3]dioxane]-2(1H),6′′-dione Chandralekha, Kuppan Gavaskar, Deivasigamani Sureshbabu, Adukamparai Rajukrishnan Lakshmi, Srinivasakannan Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, C(36)H(29)Cl(2)NO(4), two spiro links connect the methyl-substituted pyrrolidine ring to the ace­naphthyl­ene and cyclo­hexa­none rings. The cyclo­hexa­none ring is further connected to the dioxalane ring by a third spiro junction. The five-membered ring of the ace­naphthylen-1-one ring system adopts a flattened envelope conformation, with the ketonic C atom as the flap, whereas the dioxalane and pyrrolidine rings each have a twist conformation. The cyclo­hexenone ring assumes a boat conformation. An intra­molecular C—H⋯O hydrogen-bond inter­action is present. In the crystal, mol­ecules are linked by non-classical C—H⋯O hydrogen bonds, forming chains extending parallel to the a axis. International Union of Crystallography 2015-10-03 /pmc/articles/PMC4645075/ /pubmed/26594541 http://dx.doi.org/10.1107/S2056989015018034 Text en © Chandralekha et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Chandralekha, Kuppan
Gavaskar, Deivasigamani
Sureshbabu, Adukamparai Rajukrishnan
Lakshmi, Srinivasakannan
Crystal structure of 5′′-(4-chloro­benzyl­idene)-4′-(4-chloro­phen­yl)-1′-methyltri­spiro[acenapthylene-1,2′-pyrrolidine-3′,1′′-cyclo­hexane-3′′,2′′′-[1,3]dioxane]-2(1H),6′′-dione
title Crystal structure of 5′′-(4-chloro­benzyl­idene)-4′-(4-chloro­phen­yl)-1′-methyltri­spiro[acenapthylene-1,2′-pyrrolidine-3′,1′′-cyclo­hexane-3′′,2′′′-[1,3]dioxane]-2(1H),6′′-dione
title_full Crystal structure of 5′′-(4-chloro­benzyl­idene)-4′-(4-chloro­phen­yl)-1′-methyltri­spiro[acenapthylene-1,2′-pyrrolidine-3′,1′′-cyclo­hexane-3′′,2′′′-[1,3]dioxane]-2(1H),6′′-dione
title_fullStr Crystal structure of 5′′-(4-chloro­benzyl­idene)-4′-(4-chloro­phen­yl)-1′-methyltri­spiro[acenapthylene-1,2′-pyrrolidine-3′,1′′-cyclo­hexane-3′′,2′′′-[1,3]dioxane]-2(1H),6′′-dione
title_full_unstemmed Crystal structure of 5′′-(4-chloro­benzyl­idene)-4′-(4-chloro­phen­yl)-1′-methyltri­spiro[acenapthylene-1,2′-pyrrolidine-3′,1′′-cyclo­hexane-3′′,2′′′-[1,3]dioxane]-2(1H),6′′-dione
title_short Crystal structure of 5′′-(4-chloro­benzyl­idene)-4′-(4-chloro­phen­yl)-1′-methyltri­spiro[acenapthylene-1,2′-pyrrolidine-3′,1′′-cyclo­hexane-3′′,2′′′-[1,3]dioxane]-2(1H),6′′-dione
title_sort crystal structure of 5′′-(4-chloro­benzyl­idene)-4′-(4-chloro­phen­yl)-1′-methyltri­spiro[acenapthylene-1,2′-pyrrolidine-3′,1′′-cyclo­hexane-3′′,2′′′-[1,3]dioxane]-2(1h),6′′-dione
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4645075/
https://www.ncbi.nlm.nih.gov/pubmed/26594541
http://dx.doi.org/10.1107/S2056989015018034
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