Crystal structure of di­chlorido­bis­[2-(phenyl­diazen­yl)pyridine-κN (1)]zinc

The structure of the title complex, [ZnCl(2)(C(11)H(9)N(3))(2)], comprises two 2-(phenyl­diazen­yl)pyridine ligands coordin­ating to a central Zn(II) dichloride unit via the pyridyl N-atom donors, resulting in a slightly distorted tetra­hedral geometry. The complex exhibits twofold rotation symmetry...

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Detalles Bibliográficos
Autores principales: Vittaya, Luksamee, Leesakul, Nararak, Saithong, Saowanit, Chainok, Kittipong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4645076/
https://www.ncbi.nlm.nih.gov/pubmed/26594533
http://dx.doi.org/10.1107/S2056989015019143
Descripción
Sumario:The structure of the title complex, [ZnCl(2)(C(11)H(9)N(3))(2)], comprises two 2-(phenyl­diazen­yl)pyridine ligands coordin­ating to a central Zn(II) dichloride unit via the pyridyl N-atom donors, resulting in a slightly distorted tetra­hedral geometry. The complex exhibits twofold rotation symmetry, with the rotation axis bis­ecting the zinc cation. The structure is stabilized by weak inter­molecular C—H⋯Cl inter­actions [C⋯Cl = 3.411 (2) and 3.675 (2) Å], connecting neighbouring mol­ecules into layers perpendicular to the c axis.

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