Crystal structure of di­chlorido­bis­[2-(phenyl­diazen­yl)pyridine-κN (1)]zinc

The structure of the title complex, [ZnCl(2)(C(11)H(9)N(3))(2)], comprises two 2-(phenyl­diazen­yl)pyridine ligands coordin­ating to a central Zn(II) dichloride unit via the pyridyl N-atom donors, resulting in a slightly distorted tetra­hedral geometry. The complex exhibits twofold rotation symmetry...

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Autores principales: Vittaya, Luksamee, Leesakul, Nararak, Saithong, Saowanit, Chainok, Kittipong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4645076/
https://www.ncbi.nlm.nih.gov/pubmed/26594533
http://dx.doi.org/10.1107/S2056989015019143
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author Vittaya, Luksamee
Leesakul, Nararak
Saithong, Saowanit
Chainok, Kittipong
author_facet Vittaya, Luksamee
Leesakul, Nararak
Saithong, Saowanit
Chainok, Kittipong
author_sort Vittaya, Luksamee
collection PubMed
description The structure of the title complex, [ZnCl(2)(C(11)H(9)N(3))(2)], comprises two 2-(phenyl­diazen­yl)pyridine ligands coordin­ating to a central Zn(II) dichloride unit via the pyridyl N-atom donors, resulting in a slightly distorted tetra­hedral geometry. The complex exhibits twofold rotation symmetry, with the rotation axis bis­ecting the zinc cation. The structure is stabilized by weak inter­molecular C—H⋯Cl inter­actions [C⋯Cl = 3.411 (2) and 3.675 (2) Å], connecting neighbouring mol­ecules into layers perpendicular to the c axis.
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spelling pubmed-46450762015-11-20 Crystal structure of di­chlorido­bis­[2-(phenyl­diazen­yl)pyridine-κN (1)]zinc Vittaya, Luksamee Leesakul, Nararak Saithong, Saowanit Chainok, Kittipong Acta Crystallogr E Crystallogr Commun Data Reports The structure of the title complex, [ZnCl(2)(C(11)H(9)N(3))(2)], comprises two 2-(phenyl­diazen­yl)pyridine ligands coordin­ating to a central Zn(II) dichloride unit via the pyridyl N-atom donors, resulting in a slightly distorted tetra­hedral geometry. The complex exhibits twofold rotation symmetry, with the rotation axis bis­ecting the zinc cation. The structure is stabilized by weak inter­molecular C—H⋯Cl inter­actions [C⋯Cl = 3.411 (2) and 3.675 (2) Å], connecting neighbouring mol­ecules into layers perpendicular to the c axis. International Union of Crystallography 2015-10-24 /pmc/articles/PMC4645076/ /pubmed/26594533 http://dx.doi.org/10.1107/S2056989015019143 Text en © Vittaya et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Vittaya, Luksamee
Leesakul, Nararak
Saithong, Saowanit
Chainok, Kittipong
Crystal structure of di­chlorido­bis­[2-(phenyl­diazen­yl)pyridine-κN (1)]zinc
title Crystal structure of di­chlorido­bis­[2-(phenyl­diazen­yl)pyridine-κN (1)]zinc
title_full Crystal structure of di­chlorido­bis­[2-(phenyl­diazen­yl)pyridine-κN (1)]zinc
title_fullStr Crystal structure of di­chlorido­bis­[2-(phenyl­diazen­yl)pyridine-κN (1)]zinc
title_full_unstemmed Crystal structure of di­chlorido­bis­[2-(phenyl­diazen­yl)pyridine-κN (1)]zinc
title_short Crystal structure of di­chlorido­bis­[2-(phenyl­diazen­yl)pyridine-κN (1)]zinc
title_sort crystal structure of di­chlorido­bis­[2-(phenyl­diazen­yl)pyridine-κn (1)]zinc
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4645076/
https://www.ncbi.nlm.nih.gov/pubmed/26594533
http://dx.doi.org/10.1107/S2056989015019143
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