Crystal structure of the new hybrid material bis­(1,4-diazo­niabi­cyclo­[2.2.2]octa­ne) di-μ-chlorido-bis­[tetra­chlorido­bis­muthate(III)] dihydrate

The title compound bis­(1,4-diazo­niabi­cyclo­[2.2.2]octa­ne) di-μ-chlorido-bis­[tetra­chlorido­bis­muthate(III)] dihydrate, (C(6)H(14)N(2))(2)[Bi(2)Cl(10)]·2H(2)O, was ob­tain­ed by slow evaporation at room temperature of a hydro­chloric aqueous solution (pH = 1) containing bis­muth(III) nitrate an...

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Autores principales: Chouri, Marwen, Boughzala, Habib
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4645089/
https://www.ncbi.nlm.nih.gov/pubmed/26594516
http://dx.doi.org/10.1107/S2056989015019933
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author Chouri, Marwen
Boughzala, Habib
author_facet Chouri, Marwen
Boughzala, Habib
author_sort Chouri, Marwen
collection PubMed
description The title compound bis­(1,4-diazo­niabi­cyclo­[2.2.2]octa­ne) di-μ-chlorido-bis­[tetra­chlorido­bis­muthate(III)] dihydrate, (C(6)H(14)N(2))(2)[Bi(2)Cl(10)]·2H(2)O, was ob­tain­ed by slow evaporation at room temperature of a hydro­chloric aqueous solution (pH = 1) containing bis­muth(III) nitrate and 1,4-di­aza­bicyclo­[2.2.2]octane (DABCO) in a 1:2 molar ratio. The structure displays a two-dimensional arrangement parallel to (100) of isolated [Bi(2)Cl(10)](4−) bi­octa­hedra (site symmetry -1) separated by layers of organic 1,4-diazo­niabi­cyclo­[2.2.2]octane dications [(DABCOH(2))(2+)] and water mol­ecules. O—H⋯Cl, N—H⋯O and N—H⋯Cl hydrogen bonds lead to additional cohesion of the structure.
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spelling pubmed-46450892015-11-20 Crystal structure of the new hybrid material bis­(1,4-diazo­niabi­cyclo­[2.2.2]octa­ne) di-μ-chlorido-bis­[tetra­chlorido­bis­muthate(III)] dihydrate Chouri, Marwen Boughzala, Habib Acta Crystallogr E Crystallogr Commun Research Communications The title compound bis­(1,4-diazo­niabi­cyclo­[2.2.2]octa­ne) di-μ-chlorido-bis­[tetra­chlorido­bis­muthate(III)] dihydrate, (C(6)H(14)N(2))(2)[Bi(2)Cl(10)]·2H(2)O, was ob­tain­ed by slow evaporation at room temperature of a hydro­chloric aqueous solution (pH = 1) containing bis­muth(III) nitrate and 1,4-di­aza­bicyclo­[2.2.2]octane (DABCO) in a 1:2 molar ratio. The structure displays a two-dimensional arrangement parallel to (100) of isolated [Bi(2)Cl(10)](4−) bi­octa­hedra (site symmetry -1) separated by layers of organic 1,4-diazo­niabi­cyclo­[2.2.2]octane dications [(DABCOH(2))(2+)] and water mol­ecules. O—H⋯Cl, N—H⋯O and N—H⋯Cl hydrogen bonds lead to additional cohesion of the structure. International Union of Crystallography 2015-10-28 /pmc/articles/PMC4645089/ /pubmed/26594516 http://dx.doi.org/10.1107/S2056989015019933 Text en © Chouri and Boughzala 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Chouri, Marwen
Boughzala, Habib
Crystal structure of the new hybrid material bis­(1,4-diazo­niabi­cyclo­[2.2.2]octa­ne) di-μ-chlorido-bis­[tetra­chlorido­bis­muthate(III)] dihydrate
title Crystal structure of the new hybrid material bis­(1,4-diazo­niabi­cyclo­[2.2.2]octa­ne) di-μ-chlorido-bis­[tetra­chlorido­bis­muthate(III)] dihydrate
title_full Crystal structure of the new hybrid material bis­(1,4-diazo­niabi­cyclo­[2.2.2]octa­ne) di-μ-chlorido-bis­[tetra­chlorido­bis­muthate(III)] dihydrate
title_fullStr Crystal structure of the new hybrid material bis­(1,4-diazo­niabi­cyclo­[2.2.2]octa­ne) di-μ-chlorido-bis­[tetra­chlorido­bis­muthate(III)] dihydrate
title_full_unstemmed Crystal structure of the new hybrid material bis­(1,4-diazo­niabi­cyclo­[2.2.2]octa­ne) di-μ-chlorido-bis­[tetra­chlorido­bis­muthate(III)] dihydrate
title_short Crystal structure of the new hybrid material bis­(1,4-diazo­niabi­cyclo­[2.2.2]octa­ne) di-μ-chlorido-bis­[tetra­chlorido­bis­muthate(III)] dihydrate
title_sort crystal structure of the new hybrid material bis­(1,4-diazo­niabi­cyclo­[2.2.2]octa­ne) di-μ-chlorido-bis­[tetra­chlorido­bis­muthate(iii)] dihydrate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4645089/
https://www.ncbi.nlm.nih.gov/pubmed/26594516
http://dx.doi.org/10.1107/S2056989015019933
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AT boughzalahabib crystalstructureofthenewhybridmaterialbis14diazoniabicyclo222octanedimchloridobistetrachloridobismuthateiiidihydrate

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