Cargando…

Crystal structure of tetra­kis­(μ-caproato-κ(2) O:O′)bis­[(4-cyano­pyridine-κN (1))copper(II)]

The title dinuclear complex, [Cu(2)(C(6)H(11)O(2))(4)(C(6)H(4)N(2))(2)], has a paddle-wheel structure. The two crystallographically independent Cu(II) atoms are each in a distorted square-pyramidal environment, in which four O atoms from the four bridging caproate ligands form the basal plane and th...

Descripción completa

Detalles Bibliográficos
Autores principales: Baruah, Sukanya, Islam, Zinnatara, Karmakar, Sanjib, Das, Birinchi Kumar
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4645092/
https://www.ncbi.nlm.nih.gov/pubmed/26594530
http://dx.doi.org/10.1107/S2056989015019052
Descripción
Sumario:The title dinuclear complex, [Cu(2)(C(6)H(11)O(2))(4)(C(6)H(4)N(2))(2)], has a paddle-wheel structure. The two crystallographically independent Cu(II) atoms are each in a distorted square-pyramidal environment, in which four O atoms from the four bridging caproate ligands form the basal plane and the pyridine N atom of the 4-cyano­pyridine ligand occupies the apical position. The Cu⋯Cu distance is 2.6055 (9) Å. One of the alkyl chains of the caproate ligands is disordered over two sets of sites, with occupancies of 0.725 (5) and 0.275 (5). In the crystal, two pairs of C—H⋯N hydrogen bonds connect the mol­ecules into chains along [11-1] and C—H⋯O hydrogen bonds link the chains into a three-dimensional network.