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Crystal structure of tetra­kis­(μ-caproato-κ(2) O:O′)bis­[(4-cyano­pyridine-κN (1))copper(II)]

The title dinuclear complex, [Cu(2)(C(6)H(11)O(2))(4)(C(6)H(4)N(2))(2)], has a paddle-wheel structure. The two crystallographically independent Cu(II) atoms are each in a distorted square-pyramidal environment, in which four O atoms from the four bridging caproate ligands form the basal plane and th...

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Autores principales: Baruah, Sukanya, Islam, Zinnatara, Karmakar, Sanjib, Das, Birinchi Kumar
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4645092/
https://www.ncbi.nlm.nih.gov/pubmed/26594530
http://dx.doi.org/10.1107/S2056989015019052
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author Baruah, Sukanya
Islam, Zinnatara
Karmakar, Sanjib
Das, Birinchi Kumar
author_facet Baruah, Sukanya
Islam, Zinnatara
Karmakar, Sanjib
Das, Birinchi Kumar
author_sort Baruah, Sukanya
collection PubMed
description The title dinuclear complex, [Cu(2)(C(6)H(11)O(2))(4)(C(6)H(4)N(2))(2)], has a paddle-wheel structure. The two crystallographically independent Cu(II) atoms are each in a distorted square-pyramidal environment, in which four O atoms from the four bridging caproate ligands form the basal plane and the pyridine N atom of the 4-cyano­pyridine ligand occupies the apical position. The Cu⋯Cu distance is 2.6055 (9) Å. One of the alkyl chains of the caproate ligands is disordered over two sets of sites, with occupancies of 0.725 (5) and 0.275 (5). In the crystal, two pairs of C—H⋯N hydrogen bonds connect the mol­ecules into chains along [11-1] and C—H⋯O hydrogen bonds link the chains into a three-dimensional network.
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spelling pubmed-46450922015-11-20 Crystal structure of tetra­kis­(μ-caproato-κ(2) O:O′)bis­[(4-cyano­pyridine-κN (1))copper(II)] Baruah, Sukanya Islam, Zinnatara Karmakar, Sanjib Das, Birinchi Kumar Acta Crystallogr E Crystallogr Commun Data Reports The title dinuclear complex, [Cu(2)(C(6)H(11)O(2))(4)(C(6)H(4)N(2))(2)], has a paddle-wheel structure. The two crystallographically independent Cu(II) atoms are each in a distorted square-pyramidal environment, in which four O atoms from the four bridging caproate ligands form the basal plane and the pyridine N atom of the 4-cyano­pyridine ligand occupies the apical position. The Cu⋯Cu distance is 2.6055 (9) Å. One of the alkyl chains of the caproate ligands is disordered over two sets of sites, with occupancies of 0.725 (5) and 0.275 (5). In the crystal, two pairs of C—H⋯N hydrogen bonds connect the mol­ecules into chains along [11-1] and C—H⋯O hydrogen bonds link the chains into a three-dimensional network. International Union of Crystallography 2015-10-14 /pmc/articles/PMC4645092/ /pubmed/26594530 http://dx.doi.org/10.1107/S2056989015019052 Text en © Baruah et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Baruah, Sukanya
Islam, Zinnatara
Karmakar, Sanjib
Das, Birinchi Kumar
Crystal structure of tetra­kis­(μ-caproato-κ(2) O:O′)bis­[(4-cyano­pyridine-κN (1))copper(II)]
title Crystal structure of tetra­kis­(μ-caproato-κ(2) O:O′)bis­[(4-cyano­pyridine-κN (1))copper(II)]
title_full Crystal structure of tetra­kis­(μ-caproato-κ(2) O:O′)bis­[(4-cyano­pyridine-κN (1))copper(II)]
title_fullStr Crystal structure of tetra­kis­(μ-caproato-κ(2) O:O′)bis­[(4-cyano­pyridine-κN (1))copper(II)]
title_full_unstemmed Crystal structure of tetra­kis­(μ-caproato-κ(2) O:O′)bis­[(4-cyano­pyridine-κN (1))copper(II)]
title_short Crystal structure of tetra­kis­(μ-caproato-κ(2) O:O′)bis­[(4-cyano­pyridine-κN (1))copper(II)]
title_sort crystal structure of tetra­kis­(μ-caproato-κ(2) o:o′)bis­[(4-cyano­pyridine-κn (1))copper(ii)]
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4645092/
https://www.ncbi.nlm.nih.gov/pubmed/26594530
http://dx.doi.org/10.1107/S2056989015019052
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