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Crystal structure of tetrakis(μ-caproato-κ(2) O:O′)bis[(4-cyanopyridine-κN (1))copper(II)]
The title dinuclear complex, [Cu(2)(C(6)H(11)O(2))(4)(C(6)H(4)N(2))(2)], has a paddle-wheel structure. The two crystallographically independent Cu(II) atoms are each in a distorted square-pyramidal environment, in which four O atoms from the four bridging caproate ligands form the basal plane and th...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4645092/ https://www.ncbi.nlm.nih.gov/pubmed/26594530 http://dx.doi.org/10.1107/S2056989015019052 |
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author | Baruah, Sukanya Islam, Zinnatara Karmakar, Sanjib Das, Birinchi Kumar |
author_facet | Baruah, Sukanya Islam, Zinnatara Karmakar, Sanjib Das, Birinchi Kumar |
author_sort | Baruah, Sukanya |
collection | PubMed |
description | The title dinuclear complex, [Cu(2)(C(6)H(11)O(2))(4)(C(6)H(4)N(2))(2)], has a paddle-wheel structure. The two crystallographically independent Cu(II) atoms are each in a distorted square-pyramidal environment, in which four O atoms from the four bridging caproate ligands form the basal plane and the pyridine N atom of the 4-cyanopyridine ligand occupies the apical position. The Cu⋯Cu distance is 2.6055 (9) Å. One of the alkyl chains of the caproate ligands is disordered over two sets of sites, with occupancies of 0.725 (5) and 0.275 (5). In the crystal, two pairs of C—H⋯N hydrogen bonds connect the molecules into chains along [11-1] and C—H⋯O hydrogen bonds link the chains into a three-dimensional network. |
format | Online Article Text |
id | pubmed-4645092 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-46450922015-11-20 Crystal structure of tetrakis(μ-caproato-κ(2) O:O′)bis[(4-cyanopyridine-κN (1))copper(II)] Baruah, Sukanya Islam, Zinnatara Karmakar, Sanjib Das, Birinchi Kumar Acta Crystallogr E Crystallogr Commun Data Reports The title dinuclear complex, [Cu(2)(C(6)H(11)O(2))(4)(C(6)H(4)N(2))(2)], has a paddle-wheel structure. The two crystallographically independent Cu(II) atoms are each in a distorted square-pyramidal environment, in which four O atoms from the four bridging caproate ligands form the basal plane and the pyridine N atom of the 4-cyanopyridine ligand occupies the apical position. The Cu⋯Cu distance is 2.6055 (9) Å. One of the alkyl chains of the caproate ligands is disordered over two sets of sites, with occupancies of 0.725 (5) and 0.275 (5). In the crystal, two pairs of C—H⋯N hydrogen bonds connect the molecules into chains along [11-1] and C—H⋯O hydrogen bonds link the chains into a three-dimensional network. International Union of Crystallography 2015-10-14 /pmc/articles/PMC4645092/ /pubmed/26594530 http://dx.doi.org/10.1107/S2056989015019052 Text en © Baruah et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Baruah, Sukanya Islam, Zinnatara Karmakar, Sanjib Das, Birinchi Kumar Crystal structure of tetrakis(μ-caproato-κ(2) O:O′)bis[(4-cyanopyridine-κN (1))copper(II)] |
title | Crystal structure of tetrakis(μ-caproato-κ(2)
O:O′)bis[(4-cyanopyridine-κN
(1))copper(II)] |
title_full | Crystal structure of tetrakis(μ-caproato-κ(2)
O:O′)bis[(4-cyanopyridine-κN
(1))copper(II)] |
title_fullStr | Crystal structure of tetrakis(μ-caproato-κ(2)
O:O′)bis[(4-cyanopyridine-κN
(1))copper(II)] |
title_full_unstemmed | Crystal structure of tetrakis(μ-caproato-κ(2)
O:O′)bis[(4-cyanopyridine-κN
(1))copper(II)] |
title_short | Crystal structure of tetrakis(μ-caproato-κ(2)
O:O′)bis[(4-cyanopyridine-κN
(1))copper(II)] |
title_sort | crystal structure of tetrakis(μ-caproato-κ(2)
o:o′)bis[(4-cyanopyridine-κn
(1))copper(ii)] |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4645092/ https://www.ncbi.nlm.nih.gov/pubmed/26594530 http://dx.doi.org/10.1107/S2056989015019052 |
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