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Spectators Control Selectivity in Surface Chemistry: Acrolein Partial Hydrogenation Over Pd

[Image: see text] We present a mechanistic study on selective hydrogenation of acrolein over model Pd surfaces—both single crystal Pd(111) and Pd nanoparticles supported on a model oxide support. We show for the first time that selective hydrogenation of the C=O bond in acrolein to form an unsaturat...

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Detalles Bibliográficos
Autores principales: Dostert, Karl-Heinz, O’Brien, Casey P., Ivars-Barceló, Francisco, Schauermann, Swetlana, Freund, Hans-Joachim
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2015
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4646350/
https://www.ncbi.nlm.nih.gov/pubmed/26481220
http://dx.doi.org/10.1021/jacs.5b04363

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