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Spectators Control Selectivity in Surface Chemistry: Acrolein Partial Hydrogenation Over Pd
[Image: see text] We present a mechanistic study on selective hydrogenation of acrolein over model Pd surfaces—both single crystal Pd(111) and Pd nanoparticles supported on a model oxide support. We show for the first time that selective hydrogenation of the C=O bond in acrolein to form an unsaturat...
Autores principales: | Dostert, Karl-Heinz, O’Brien, Casey P., Ivars-Barceló, Francisco, Schauermann, Swetlana, Freund, Hans-Joachim |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical
Society
2015
|
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4646350/ https://www.ncbi.nlm.nih.gov/pubmed/26481220 http://dx.doi.org/10.1021/jacs.5b04363 |
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