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Crystal structure of ethyl 2-phenyl-9-phenylsulfonyl-9H-carbazole-3-carboxylate
In the title compound, C(27)H(21)NO(4)S, the dihedral angles between the carbazole ring system (r.m.s. deviation = 0.015 Å) and the sulfur-bonded and directly linked benzene rings are 79.98 (11) and 53.51 (18)°, respectively. The benzene rings subtend a dihedral angle of 48.4 (2)°. The ethyl side ch...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647343/ https://www.ncbi.nlm.nih.gov/pubmed/26594444 http://dx.doi.org/10.1107/S205698901501662X |
Sumario: | In the title compound, C(27)H(21)NO(4)S, the dihedral angles between the carbazole ring system (r.m.s. deviation = 0.015 Å) and the sulfur-bonded and directly linked benzene rings are 79.98 (11) and 53.51 (18)°, respectively. The benzene rings subtend a dihedral angle of 48.4 (2)°. The ethyl side chain of the ester group has an extended conformation [C—O—C—C = −172.3 (3)°]. In the crystal, inversion dimers linked by pairs of weak C—H⋯O hydrogen bonds generate R (2) (2)(22) loops. The dimers are linked by weak C—H⋯π and π–π [centroid-to-centroid distances ranging from 3.5042 (14) to 3.888 (2) Å] interactions, thereby forming a three-dimensional supramolecular network. |
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