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Crystal structure of ethyl 2-phenyl-9-phenyl­sulfonyl-9H-carbazole-3-carboxyl­ate

In the title compound, C(27)H(21)NO(4)S, the dihedral angles between the carbazole ring system (r.m.s. deviation = 0.015 Å) and the sulfur-bonded and directly linked benzene rings are 79.98 (11) and 53.51 (18)°, respectively. The benzene rings subtend a dihedral angle of 48.4 (2)°. The ethyl side ch...

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Autores principales: Umadevi, M., Raju, P., Yamuna, R., Mohanakrishnan, A. K., Chakkaravarthi, G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647343/
https://www.ncbi.nlm.nih.gov/pubmed/26594444
http://dx.doi.org/10.1107/S205698901501662X
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author Umadevi, M.
Raju, P.
Yamuna, R.
Mohanakrishnan, A. K.
Chakkaravarthi, G.
author_facet Umadevi, M.
Raju, P.
Yamuna, R.
Mohanakrishnan, A. K.
Chakkaravarthi, G.
author_sort Umadevi, M.
collection PubMed
description In the title compound, C(27)H(21)NO(4)S, the dihedral angles between the carbazole ring system (r.m.s. deviation = 0.015 Å) and the sulfur-bonded and directly linked benzene rings are 79.98 (11) and 53.51 (18)°, respectively. The benzene rings subtend a dihedral angle of 48.4 (2)°. The ethyl side chain of the ester group has an extended conformation [C—O—C—C = −172.3 (3)°]. In the crystal, inversion dimers linked by pairs of weak C—H⋯O hydrogen bonds generate R (2) (2)(22) loops. The dimers are linked by weak C—H⋯π and π–π [centroid-to-centroid distances ranging from 3.5042 (14) to 3.888 (2) Å] inter­actions, thereby forming a three-dimensional supra­molecular network.
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spelling pubmed-46473432015-11-20 Crystal structure of ethyl 2-phenyl-9-phenyl­sulfonyl-9H-carbazole-3-carboxyl­ate Umadevi, M. Raju, P. Yamuna, R. Mohanakrishnan, A. K. Chakkaravarthi, G. Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, C(27)H(21)NO(4)S, the dihedral angles between the carbazole ring system (r.m.s. deviation = 0.015 Å) and the sulfur-bonded and directly linked benzene rings are 79.98 (11) and 53.51 (18)°, respectively. The benzene rings subtend a dihedral angle of 48.4 (2)°. The ethyl side chain of the ester group has an extended conformation [C—O—C—C = −172.3 (3)°]. In the crystal, inversion dimers linked by pairs of weak C—H⋯O hydrogen bonds generate R (2) (2)(22) loops. The dimers are linked by weak C—H⋯π and π–π [centroid-to-centroid distances ranging from 3.5042 (14) to 3.888 (2) Å] inter­actions, thereby forming a three-dimensional supra­molecular network. International Union of Crystallography 2015-09-12 /pmc/articles/PMC4647343/ /pubmed/26594444 http://dx.doi.org/10.1107/S205698901501662X Text en © Umadevi et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Umadevi, M.
Raju, P.
Yamuna, R.
Mohanakrishnan, A. K.
Chakkaravarthi, G.
Crystal structure of ethyl 2-phenyl-9-phenyl­sulfonyl-9H-carbazole-3-carboxyl­ate
title Crystal structure of ethyl 2-phenyl-9-phenyl­sulfonyl-9H-carbazole-3-carboxyl­ate
title_full Crystal structure of ethyl 2-phenyl-9-phenyl­sulfonyl-9H-carbazole-3-carboxyl­ate
title_fullStr Crystal structure of ethyl 2-phenyl-9-phenyl­sulfonyl-9H-carbazole-3-carboxyl­ate
title_full_unstemmed Crystal structure of ethyl 2-phenyl-9-phenyl­sulfonyl-9H-carbazole-3-carboxyl­ate
title_short Crystal structure of ethyl 2-phenyl-9-phenyl­sulfonyl-9H-carbazole-3-carboxyl­ate
title_sort crystal structure of ethyl 2-phenyl-9-phenyl­sulfonyl-9h-carbazole-3-carboxyl­ate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647343/
https://www.ncbi.nlm.nih.gov/pubmed/26594444
http://dx.doi.org/10.1107/S205698901501662X
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