Cargando…
Crystal structure of ethyl 2-phenyl-9-phenylsulfonyl-9H-carbazole-3-carboxylate
In the title compound, C(27)H(21)NO(4)S, the dihedral angles between the carbazole ring system (r.m.s. deviation = 0.015 Å) and the sulfur-bonded and directly linked benzene rings are 79.98 (11) and 53.51 (18)°, respectively. The benzene rings subtend a dihedral angle of 48.4 (2)°. The ethyl side ch...
Autores principales: | , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647343/ https://www.ncbi.nlm.nih.gov/pubmed/26594444 http://dx.doi.org/10.1107/S205698901501662X |
_version_ | 1782401077644099584 |
---|---|
author | Umadevi, M. Raju, P. Yamuna, R. Mohanakrishnan, A. K. Chakkaravarthi, G. |
author_facet | Umadevi, M. Raju, P. Yamuna, R. Mohanakrishnan, A. K. Chakkaravarthi, G. |
author_sort | Umadevi, M. |
collection | PubMed |
description | In the title compound, C(27)H(21)NO(4)S, the dihedral angles between the carbazole ring system (r.m.s. deviation = 0.015 Å) and the sulfur-bonded and directly linked benzene rings are 79.98 (11) and 53.51 (18)°, respectively. The benzene rings subtend a dihedral angle of 48.4 (2)°. The ethyl side chain of the ester group has an extended conformation [C—O—C—C = −172.3 (3)°]. In the crystal, inversion dimers linked by pairs of weak C—H⋯O hydrogen bonds generate R (2) (2)(22) loops. The dimers are linked by weak C—H⋯π and π–π [centroid-to-centroid distances ranging from 3.5042 (14) to 3.888 (2) Å] interactions, thereby forming a three-dimensional supramolecular network. |
format | Online Article Text |
id | pubmed-4647343 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-46473432015-11-20 Crystal structure of ethyl 2-phenyl-9-phenylsulfonyl-9H-carbazole-3-carboxylate Umadevi, M. Raju, P. Yamuna, R. Mohanakrishnan, A. K. Chakkaravarthi, G. Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, C(27)H(21)NO(4)S, the dihedral angles between the carbazole ring system (r.m.s. deviation = 0.015 Å) and the sulfur-bonded and directly linked benzene rings are 79.98 (11) and 53.51 (18)°, respectively. The benzene rings subtend a dihedral angle of 48.4 (2)°. The ethyl side chain of the ester group has an extended conformation [C—O—C—C = −172.3 (3)°]. In the crystal, inversion dimers linked by pairs of weak C—H⋯O hydrogen bonds generate R (2) (2)(22) loops. The dimers are linked by weak C—H⋯π and π–π [centroid-to-centroid distances ranging from 3.5042 (14) to 3.888 (2) Å] interactions, thereby forming a three-dimensional supramolecular network. International Union of Crystallography 2015-09-12 /pmc/articles/PMC4647343/ /pubmed/26594444 http://dx.doi.org/10.1107/S205698901501662X Text en © Umadevi et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Umadevi, M. Raju, P. Yamuna, R. Mohanakrishnan, A. K. Chakkaravarthi, G. Crystal structure of ethyl 2-phenyl-9-phenylsulfonyl-9H-carbazole-3-carboxylate |
title | Crystal structure of ethyl 2-phenyl-9-phenylsulfonyl-9H-carbazole-3-carboxylate |
title_full | Crystal structure of ethyl 2-phenyl-9-phenylsulfonyl-9H-carbazole-3-carboxylate |
title_fullStr | Crystal structure of ethyl 2-phenyl-9-phenylsulfonyl-9H-carbazole-3-carboxylate |
title_full_unstemmed | Crystal structure of ethyl 2-phenyl-9-phenylsulfonyl-9H-carbazole-3-carboxylate |
title_short | Crystal structure of ethyl 2-phenyl-9-phenylsulfonyl-9H-carbazole-3-carboxylate |
title_sort | crystal structure of ethyl 2-phenyl-9-phenylsulfonyl-9h-carbazole-3-carboxylate |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647343/ https://www.ncbi.nlm.nih.gov/pubmed/26594444 http://dx.doi.org/10.1107/S205698901501662X |
work_keys_str_mv | AT umadevim crystalstructureofethyl2phenyl9phenylsulfonyl9hcarbazole3carboxylate AT rajup crystalstructureofethyl2phenyl9phenylsulfonyl9hcarbazole3carboxylate AT yamunar crystalstructureofethyl2phenyl9phenylsulfonyl9hcarbazole3carboxylate AT mohanakrishnanak crystalstructureofethyl2phenyl9phenylsulfonyl9hcarbazole3carboxylate AT chakkaravarthig crystalstructureofethyl2phenyl9phenylsulfonyl9hcarbazole3carboxylate |