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Crystal structure of 2-meth­oxy-1-nitro­naphthalene

The asymmetric unit of the title compound, C(11)H(9)NO(3), contains two mol­ecules, A and B. In mol­ecule A, the dihedral angle between the planes of the naphthalene ring system (r.m.s. deviation = 0.003 Å) and the nitro group is 89.9 (2)°, and the C atom of the meth­oxy group deviates from the naph...

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Autores principales: Yassine, Hasna, Khouili, Mostafa, El Ammari, Lahcen, Saadi, Mohamed, Ketatni, El Mostafa
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647346/
https://www.ncbi.nlm.nih.gov/pubmed/26594431
http://dx.doi.org/10.1107/S2056989015016114
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author Yassine, Hasna
Khouili, Mostafa
El Ammari, Lahcen
Saadi, Mohamed
Ketatni, El Mostafa
author_facet Yassine, Hasna
Khouili, Mostafa
El Ammari, Lahcen
Saadi, Mohamed
Ketatni, El Mostafa
author_sort Yassine, Hasna
collection PubMed
description The asymmetric unit of the title compound, C(11)H(9)NO(3), contains two mol­ecules, A and B. In mol­ecule A, the dihedral angle between the planes of the naphthalene ring system (r.m.s. deviation = 0.003 Å) and the nitro group is 89.9 (2)°, and the C atom of the meth­oxy group deviates from the naphthyl plane by 0.022 (2) Å. Equivalent data for mol­ecule B are 0.008 Å, 65.9 (2)° and −0.198 (2) Å, respectively. In the crystal, mol­ecules are linked by weak C—H⋯O inter­actions, forming [100] chains of alternating A and B mol­ecules. Weak aromatic π–π stacking contacts, with a range of centroid–centroid distances from 3.5863 (9) to 3.8048 (9) Å, are also observed.
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spelling pubmed-46473462015-11-20 Crystal structure of 2-meth­oxy-1-nitro­naphthalene Yassine, Hasna Khouili, Mostafa El Ammari, Lahcen Saadi, Mohamed Ketatni, El Mostafa Acta Crystallogr E Crystallogr Commun Data Reports The asymmetric unit of the title compound, C(11)H(9)NO(3), contains two mol­ecules, A and B. In mol­ecule A, the dihedral angle between the planes of the naphthalene ring system (r.m.s. deviation = 0.003 Å) and the nitro group is 89.9 (2)°, and the C atom of the meth­oxy group deviates from the naphthyl plane by 0.022 (2) Å. Equivalent data for mol­ecule B are 0.008 Å, 65.9 (2)° and −0.198 (2) Å, respectively. In the crystal, mol­ecules are linked by weak C—H⋯O inter­actions, forming [100] chains of alternating A and B mol­ecules. Weak aromatic π–π stacking contacts, with a range of centroid–centroid distances from 3.5863 (9) to 3.8048 (9) Å, are also observed. International Union of Crystallography 2015-09-12 /pmc/articles/PMC4647346/ /pubmed/26594431 http://dx.doi.org/10.1107/S2056989015016114 Text en © Yassine et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Yassine, Hasna
Khouili, Mostafa
El Ammari, Lahcen
Saadi, Mohamed
Ketatni, El Mostafa
Crystal structure of 2-meth­oxy-1-nitro­naphthalene
title Crystal structure of 2-meth­oxy-1-nitro­naphthalene
title_full Crystal structure of 2-meth­oxy-1-nitro­naphthalene
title_fullStr Crystal structure of 2-meth­oxy-1-nitro­naphthalene
title_full_unstemmed Crystal structure of 2-meth­oxy-1-nitro­naphthalene
title_short Crystal structure of 2-meth­oxy-1-nitro­naphthalene
title_sort crystal structure of 2-meth­oxy-1-nitro­naphthalene
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647346/
https://www.ncbi.nlm.nih.gov/pubmed/26594431
http://dx.doi.org/10.1107/S2056989015016114
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