Crystal structure of (μ-4-hy­droxy­benzene­thiol­ato-κ(2) S:S)bis­(μ-phenyl­methane­thiol­ato-κ(2) S:S)bis­[(η(6)-1-isopropyl-4-methyl­benzene)­ruthenium(II)] tetra­fluorido­borate

The crystal structure of the dinuclear arene ruthenium title complex, [Ru(2)(C(6)H(5)OS)(C(7)H(7)S)(2)(C(10)H(14))(2)]BF(4), shows the two Ru(II) atoms to be bridged by two benzyl­thio­pheno­late units and one 4-hy­droxy­thio­pheno­late unit, with the remaining three coordination sites of each Ru(II...

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Detalles Bibliográficos
Autores principales: Stíbal, David, Süss-Fink, Georg, Therrien, Bruno
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647355/
https://www.ncbi.nlm.nih.gov/pubmed/26594399
http://dx.doi.org/10.1107/S2056989015016953
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author Stíbal, David
Süss-Fink, Georg
Therrien, Bruno
author_facet Stíbal, David
Süss-Fink, Georg
Therrien, Bruno
author_sort Stíbal, David
collection PubMed
description The crystal structure of the dinuclear arene ruthenium title complex, [Ru(2)(C(6)H(5)OS)(C(7)H(7)S)(2)(C(10)H(14))(2)]BF(4), shows the two Ru(II) atoms to be bridged by two benzyl­thio­pheno­late units and one 4-hy­droxy­thio­pheno­late unit, with the remaining three coordination sites of each Ru(II) atom being occupied by p-cymene ligands, completing the typical piano-stool coordination geometry. The BF(4) (−) counter-anion is surrounded by four cationic dinuclear complexes, showing an O—H⋯F hydrogen bond and several weak C—H⋯F inter­actions. This is the first example of an X-ray analysis of a mixed dinuclear tri­thiol­ate arene ruthenium(II) complex.
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spelling pubmed-46473552015-11-20 Crystal structure of (μ-4-hy­droxy­benzene­thiol­ato-κ(2) S:S)bis­(μ-phenyl­methane­thiol­ato-κ(2) S:S)bis­[(η(6)-1-isopropyl-4-methyl­benzene)­ruthenium(II)] tetra­fluorido­borate Stíbal, David Süss-Fink, Georg Therrien, Bruno Acta Crystallogr E Crystallogr Commun Research Communications The crystal structure of the dinuclear arene ruthenium title complex, [Ru(2)(C(6)H(5)OS)(C(7)H(7)S)(2)(C(10)H(14))(2)]BF(4), shows the two Ru(II) atoms to be bridged by two benzyl­thio­pheno­late units and one 4-hy­droxy­thio­pheno­late unit, with the remaining three coordination sites of each Ru(II) atom being occupied by p-cymene ligands, completing the typical piano-stool coordination geometry. The BF(4) (−) counter-anion is surrounded by four cationic dinuclear complexes, showing an O—H⋯F hydrogen bond and several weak C—H⋯F inter­actions. This is the first example of an X-ray analysis of a mixed dinuclear tri­thiol­ate arene ruthenium(II) complex. International Union of Crystallography 2015-09-12 /pmc/articles/PMC4647355/ /pubmed/26594399 http://dx.doi.org/10.1107/S2056989015016953 Text en © Stíbal et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Stíbal, David
Süss-Fink, Georg
Therrien, Bruno
Crystal structure of (μ-4-hy­droxy­benzene­thiol­ato-κ(2) S:S)bis­(μ-phenyl­methane­thiol­ato-κ(2) S:S)bis­[(η(6)-1-isopropyl-4-methyl­benzene)­ruthenium(II)] tetra­fluorido­borate
title Crystal structure of (μ-4-hy­droxy­benzene­thiol­ato-κ(2) S:S)bis­(μ-phenyl­methane­thiol­ato-κ(2) S:S)bis­[(η(6)-1-isopropyl-4-methyl­benzene)­ruthenium(II)] tetra­fluorido­borate
title_full Crystal structure of (μ-4-hy­droxy­benzene­thiol­ato-κ(2) S:S)bis­(μ-phenyl­methane­thiol­ato-κ(2) S:S)bis­[(η(6)-1-isopropyl-4-methyl­benzene)­ruthenium(II)] tetra­fluorido­borate
title_fullStr Crystal structure of (μ-4-hy­droxy­benzene­thiol­ato-κ(2) S:S)bis­(μ-phenyl­methane­thiol­ato-κ(2) S:S)bis­[(η(6)-1-isopropyl-4-methyl­benzene)­ruthenium(II)] tetra­fluorido­borate
title_full_unstemmed Crystal structure of (μ-4-hy­droxy­benzene­thiol­ato-κ(2) S:S)bis­(μ-phenyl­methane­thiol­ato-κ(2) S:S)bis­[(η(6)-1-isopropyl-4-methyl­benzene)­ruthenium(II)] tetra­fluorido­borate
title_short Crystal structure of (μ-4-hy­droxy­benzene­thiol­ato-κ(2) S:S)bis­(μ-phenyl­methane­thiol­ato-κ(2) S:S)bis­[(η(6)-1-isopropyl-4-methyl­benzene)­ruthenium(II)] tetra­fluorido­borate
title_sort crystal structure of (μ-4-hy­droxy­benzene­thiol­ato-κ(2) s:s)bis­(μ-phenyl­methane­thiol­ato-κ(2) s:s)bis­[(η(6)-1-isopropyl-4-methyl­benzene)­ruthenium(ii)] tetra­fluorido­borate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647355/
https://www.ncbi.nlm.nih.gov/pubmed/26594399
http://dx.doi.org/10.1107/S2056989015016953
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