Crystal structure of poly[(2,2′-bi­pyridine-κ(2) N,N′)tetra-μ(2)-cyanido-κ(4) C:N;κ(4) N:C-manganese(II)disilver(I)]

The title compound, [Ag(2)Mn(CN)(4)(C(10)H(8)N(2))](n) or Mn(bipy){Ag(CN)(2)}(2) (bipy = 2,2′-bi­pyridine) is isostructural with Cd(bipy){Au(CN)(2)}(2) [Guo et al. (2009 ▸). CrystEngComm, 11, 61–66]. The Mn(II) atom has crystallographically imposed twofold symmetry and a distorted octa­hedral coordi...

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Detalles Bibliográficos
Autores principales: Theppitak, Chatphorn, Chainok, Kittipong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647358/
https://www.ncbi.nlm.nih.gov/pubmed/26594425
http://dx.doi.org/10.1107/S205698901501676X
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author Theppitak, Chatphorn
Chainok, Kittipong
author_facet Theppitak, Chatphorn
Chainok, Kittipong
author_sort Theppitak, Chatphorn
collection PubMed
description The title compound, [Ag(2)Mn(CN)(4)(C(10)H(8)N(2))](n) or Mn(bipy){Ag(CN)(2)}(2) (bipy = 2,2′-bi­pyridine) is isostructural with Cd(bipy){Au(CN)(2)}(2) [Guo et al. (2009 ▸). CrystEngComm, 11, 61–66]. The Mn(II) atom has crystallographically imposed twofold symmetry and a distorted octa­hedral coordination sphere consisting of six N atoms from one bi­pyridine ligand and four di­cyano­argentate(I) anions, [Ag(CN)(2)](−), while the Ag(I) atom of the complex anion displays the expected linear geometry. Each [Ag(CN)(2)](−) unit connects to two neighbouring [Mn(bipy)](2+) cations to give an threefold inter­penetrating quartz-like three-dimensional framework. No directional inter­actions beyond van der Waals contacts are observed.
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spelling pubmed-46473582015-11-20 Crystal structure of poly[(2,2′-bi­pyridine-κ(2) N,N′)tetra-μ(2)-cyanido-κ(4) C:N;κ(4) N:C-manganese(II)disilver(I)] Theppitak, Chatphorn Chainok, Kittipong Acta Crystallogr E Crystallogr Commun Data Reports The title compound, [Ag(2)Mn(CN)(4)(C(10)H(8)N(2))](n) or Mn(bipy){Ag(CN)(2)}(2) (bipy = 2,2′-bi­pyridine) is isostructural with Cd(bipy){Au(CN)(2)}(2) [Guo et al. (2009 ▸). CrystEngComm, 11, 61–66]. The Mn(II) atom has crystallographically imposed twofold symmetry and a distorted octa­hedral coordination sphere consisting of six N atoms from one bi­pyridine ligand and four di­cyano­argentate(I) anions, [Ag(CN)(2)](−), while the Ag(I) atom of the complex anion displays the expected linear geometry. Each [Ag(CN)(2)](−) unit connects to two neighbouring [Mn(bipy)](2+) cations to give an threefold inter­penetrating quartz-like three-dimensional framework. No directional inter­actions beyond van der Waals contacts are observed. International Union of Crystallography 2015-09-12 /pmc/articles/PMC4647358/ /pubmed/26594425 http://dx.doi.org/10.1107/S205698901501676X Text en © Theppitak and Chainok 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Theppitak, Chatphorn
Chainok, Kittipong
Crystal structure of poly[(2,2′-bi­pyridine-κ(2) N,N′)tetra-μ(2)-cyanido-κ(4) C:N;κ(4) N:C-manganese(II)disilver(I)]
title Crystal structure of poly[(2,2′-bi­pyridine-κ(2) N,N′)tetra-μ(2)-cyanido-κ(4) C:N;κ(4) N:C-manganese(II)disilver(I)]
title_full Crystal structure of poly[(2,2′-bi­pyridine-κ(2) N,N′)tetra-μ(2)-cyanido-κ(4) C:N;κ(4) N:C-manganese(II)disilver(I)]
title_fullStr Crystal structure of poly[(2,2′-bi­pyridine-κ(2) N,N′)tetra-μ(2)-cyanido-κ(4) C:N;κ(4) N:C-manganese(II)disilver(I)]
title_full_unstemmed Crystal structure of poly[(2,2′-bi­pyridine-κ(2) N,N′)tetra-μ(2)-cyanido-κ(4) C:N;κ(4) N:C-manganese(II)disilver(I)]
title_short Crystal structure of poly[(2,2′-bi­pyridine-κ(2) N,N′)tetra-μ(2)-cyanido-κ(4) C:N;κ(4) N:C-manganese(II)disilver(I)]
title_sort crystal structure of poly[(2,2′-bi­pyridine-κ(2) n,n′)tetra-μ(2)-cyanido-κ(4) c:n;κ(4) n:c-manganese(ii)disilver(i)]
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647358/
https://www.ncbi.nlm.nih.gov/pubmed/26594425
http://dx.doi.org/10.1107/S205698901501676X
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