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Crystal structure of dimethyl 9H-carbazole-2,7-di­carb­oxy­late

In the title compound, C(16)H(13)NO(4), the carbazole ring system is almost planar with non-H atoms possessing a mean deviation from planarity of 0.037 Å. The two ester groups are orientated trans to one another and tilted slightly from the mean plane of the carbazole ring system, making dihedral an...

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Detalles Bibliográficos
Autores principales: Lehane, Ryan L., Golen, James A., Rheingold, Arnold L., Manke, David R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647360/
https://www.ncbi.nlm.nih.gov/pubmed/26594478
http://dx.doi.org/10.1107/S2056989015017557
Descripción
Sumario:In the title compound, C(16)H(13)NO(4), the carbazole ring system is almost planar with non-H atoms possessing a mean deviation from planarity of 0.037 Å. The two ester groups are orientated trans to one another and tilted slightly from the mean plane of the carbazole ring system, making dihedral angles of 8.12 (6) and 8.21 (5)°. In the crystal, mol­ecules are linked by pairs of N—H⋯O hydrogen bonds forming inversion dimers. The dimers are linked by parallel slipped π–π inter­actions, forming slabs propagating along the b-axis direction [inter-centroid distance = 3.6042 (8) Å, inter-planar distance = 3.3437 (5) Å, slippage = 1.345 Å].