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Crystal structure of N,N,N-tris[(1,3-benzothiazol-2-yl)methyl]amine
The title compound, C(24)H(18)N(4)S(3), exhibits three near planar benzothiazole systems in a pseudo-C (3) conformation. The dihedral angles between the planes of the benzothiazole groups range from 112.56 (4) to 124.68 (4)° In the crystal, molecules are connected to each other through three sh...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647366/ https://www.ncbi.nlm.nih.gov/pubmed/26594479 http://dx.doi.org/10.1107/S2056989015017417 |
Sumario: | The title compound, C(24)H(18)N(4)S(3), exhibits three near planar benzothiazole systems in a pseudo-C (3) conformation. The dihedral angles between the planes of the benzothiazole groups range from 112.56 (4) to 124.68 (4)° In the crystal, molecules are connected to each other through three short C—H⋯N contacts, forming an infinite chain along [100]. The molecules are also linked by π–π interactions with each of the three five-membered thiazole rings. [inter-centroid distance range: 3.614 (1)–4.074 (1) Å, inter-planar distance range: 3.4806 (17)–3.6902 (15) Å, slippage range: 0.759 (3)–1.887 (3) Å]. |
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