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Crystal structure of N,N,N-tris[(1,3-benzothiazol-2-yl)methyl]amine
The title compound, C(24)H(18)N(4)S(3), exhibits three near planar benzothiazole systems in a pseudo-C (3) conformation. The dihedral angles between the planes of the benzothiazole groups range from 112.56 (4) to 124.68 (4)° In the crystal, molecules are connected to each other through three sh...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2015
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647366/ https://www.ncbi.nlm.nih.gov/pubmed/26594479 http://dx.doi.org/10.1107/S2056989015017417 |
| _version_ | 1782401082804142080 |
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| author | Mdluli, Velabo Golen, James A. Rheingold, Arnold L. Manke, David R. |
| author_facet | Mdluli, Velabo Golen, James A. Rheingold, Arnold L. Manke, David R. |
| author_sort | Mdluli, Velabo |
| collection | PubMed |
| description | The title compound, C(24)H(18)N(4)S(3), exhibits three near planar benzothiazole systems in a pseudo-C (3) conformation. The dihedral angles between the planes of the benzothiazole groups range from 112.56 (4) to 124.68 (4)° In the crystal, molecules are connected to each other through three short C—H⋯N contacts, forming an infinite chain along [100]. The molecules are also linked by π–π interactions with each of the three five-membered thiazole rings. [inter-centroid distance range: 3.614 (1)–4.074 (1) Å, inter-planar distance range: 3.4806 (17)–3.6902 (15) Å, slippage range: 0.759 (3)–1.887 (3) Å]. |
| format | Online Article Text |
| id | pubmed-4647366 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2015 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-46473662015-11-20 Crystal structure of N,N,N-tris[(1,3-benzothiazol-2-yl)methyl]amine Mdluli, Velabo Golen, James A. Rheingold, Arnold L. Manke, David R. Acta Crystallogr E Crystallogr Commun Data Reports The title compound, C(24)H(18)N(4)S(3), exhibits three near planar benzothiazole systems in a pseudo-C (3) conformation. The dihedral angles between the planes of the benzothiazole groups range from 112.56 (4) to 124.68 (4)° In the crystal, molecules are connected to each other through three short C—H⋯N contacts, forming an infinite chain along [100]. The molecules are also linked by π–π interactions with each of the three five-membered thiazole rings. [inter-centroid distance range: 3.614 (1)–4.074 (1) Å, inter-planar distance range: 3.4806 (17)–3.6902 (15) Å, slippage range: 0.759 (3)–1.887 (3) Å]. International Union of Crystallography 2015-09-26 /pmc/articles/PMC4647366/ /pubmed/26594479 http://dx.doi.org/10.1107/S2056989015017417 Text en © Mdluli et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Data Reports Mdluli, Velabo Golen, James A. Rheingold, Arnold L. Manke, David R. Crystal structure of N,N,N-tris[(1,3-benzothiazol-2-yl)methyl]amine |
| title | Crystal structure of N,N,N-tris[(1,3-benzothiazol-2-yl)methyl]amine |
| title_full | Crystal structure of N,N,N-tris[(1,3-benzothiazol-2-yl)methyl]amine |
| title_fullStr | Crystal structure of N,N,N-tris[(1,3-benzothiazol-2-yl)methyl]amine |
| title_full_unstemmed | Crystal structure of N,N,N-tris[(1,3-benzothiazol-2-yl)methyl]amine |
| title_short | Crystal structure of N,N,N-tris[(1,3-benzothiazol-2-yl)methyl]amine |
| title_sort | crystal structure of n,n,n-tris[(1,3-benzothiazol-2-yl)methyl]amine |
| topic | Data Reports |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647366/ https://www.ncbi.nlm.nih.gov/pubmed/26594479 http://dx.doi.org/10.1107/S2056989015017417 |
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