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Crystal structure of bis­[μ-(4-meth­oxy­phen­yl)methane­thiol­ato-κ(2) S:S]bis­[chlorido­(η(6)-1-isopropyl-4-methyl­benzene)­ruthenium(II)] chloro­form disolvate

The mol­ecular structure of the title complex, [Ru(2)(C(8)H(9)OS)(2)Cl(2)(C(10)H(14))(2)]·2CHCl(3) or (p-MeC(6)H(4)Pr(i))(2)Ru(2)(SCH(2)-p-C(6)H(5)-OCH(3))(2)Cl(2)·2CHCl(3), shows inversion symmetry. The two symmetry-related Ru(II) atoms are bridged by two 4-meth­oxy-α-toluene­thiol­ato [(4-meth­oxy...

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Detalles Bibliográficos
Autores principales: Stíbal, David, Süss-Fink, Georg, Therrien, Bruno
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647371/
https://www.ncbi.nlm.nih.gov/pubmed/26594410
http://dx.doi.org/10.1107/S2056989015017399
Descripción
Sumario:The mol­ecular structure of the title complex, [Ru(2)(C(8)H(9)OS)(2)Cl(2)(C(10)H(14))(2)]·2CHCl(3) or (p-MeC(6)H(4)Pr(i))(2)Ru(2)(SCH(2)-p-C(6)H(5)-OCH(3))(2)Cl(2)·2CHCl(3), shows inversion symmetry. The two symmetry-related Ru(II) atoms are bridged by two 4-meth­oxy-α-toluene­thiol­ato [(4-meth­oxy­phen­yl)methane­thiol­ato] units. One chlorido ligand and the p-cymene ligand complete the typical piano-stool coordination environment of the Ru(II) atom. In the crystal, the CH moiety of the chloro­form mol­ecule inter­acts with the chlorido ligand of the dinuclear complex, while one Cl atom of the solvent inter­acts more weakly with the methyl group of the bridging 4-meth­oxy-α-toluene­thiol­ato unit. This assembly leads to the formation of supra­molecular chains extending parallel to [021].