Crystal structure of bis­[μ-(4-meth­oxy­phen­yl)methane­thiol­ato-κ(2) S:S]bis­[chlorido­(η(6)-1-isopropyl-4-methyl­benzene)­ruthenium(II)] chloro­form disolvate

The mol­ecular structure of the title complex, [Ru(2)(C(8)H(9)OS)(2)Cl(2)(C(10)H(14))(2)]·2CHCl(3) or (p-MeC(6)H(4)Pr(i))(2)Ru(2)(SCH(2)-p-C(6)H(5)-OCH(3))(2)Cl(2)·2CHCl(3), shows inversion symmetry. The two symmetry-related Ru(II) atoms are bridged by two 4-meth­oxy-α-toluene­thiol­ato [(4-meth­oxy...

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Detalles Bibliográficos
Autores principales: Stíbal, David, Süss-Fink, Georg, Therrien, Bruno
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647371/
https://www.ncbi.nlm.nih.gov/pubmed/26594410
http://dx.doi.org/10.1107/S2056989015017399
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author Stíbal, David
Süss-Fink, Georg
Therrien, Bruno
author_facet Stíbal, David
Süss-Fink, Georg
Therrien, Bruno
author_sort Stíbal, David
collection PubMed
description The mol­ecular structure of the title complex, [Ru(2)(C(8)H(9)OS)(2)Cl(2)(C(10)H(14))(2)]·2CHCl(3) or (p-MeC(6)H(4)Pr(i))(2)Ru(2)(SCH(2)-p-C(6)H(5)-OCH(3))(2)Cl(2)·2CHCl(3), shows inversion symmetry. The two symmetry-related Ru(II) atoms are bridged by two 4-meth­oxy-α-toluene­thiol­ato [(4-meth­oxy­phen­yl)methane­thiol­ato] units. One chlorido ligand and the p-cymene ligand complete the typical piano-stool coordination environment of the Ru(II) atom. In the crystal, the CH moiety of the chloro­form mol­ecule inter­acts with the chlorido ligand of the dinuclear complex, while one Cl atom of the solvent inter­acts more weakly with the methyl group of the bridging 4-meth­oxy-α-toluene­thiol­ato unit. This assembly leads to the formation of supra­molecular chains extending parallel to [021].
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spelling pubmed-46473712015-11-20 Crystal structure of bis­[μ-(4-meth­oxy­phen­yl)methane­thiol­ato-κ(2) S:S]bis­[chlorido­(η(6)-1-isopropyl-4-methyl­benzene)­ruthenium(II)] chloro­form disolvate Stíbal, David Süss-Fink, Georg Therrien, Bruno Acta Crystallogr E Crystallogr Commun Research Communications The mol­ecular structure of the title complex, [Ru(2)(C(8)H(9)OS)(2)Cl(2)(C(10)H(14))(2)]·2CHCl(3) or (p-MeC(6)H(4)Pr(i))(2)Ru(2)(SCH(2)-p-C(6)H(5)-OCH(3))(2)Cl(2)·2CHCl(3), shows inversion symmetry. The two symmetry-related Ru(II) atoms are bridged by two 4-meth­oxy-α-toluene­thiol­ato [(4-meth­oxy­phen­yl)methane­thiol­ato] units. One chlorido ligand and the p-cymene ligand complete the typical piano-stool coordination environment of the Ru(II) atom. In the crystal, the CH moiety of the chloro­form mol­ecule inter­acts with the chlorido ligand of the dinuclear complex, while one Cl atom of the solvent inter­acts more weakly with the methyl group of the bridging 4-meth­oxy-α-toluene­thiol­ato unit. This assembly leads to the formation of supra­molecular chains extending parallel to [021]. International Union of Crystallography 2015-09-26 /pmc/articles/PMC4647371/ /pubmed/26594410 http://dx.doi.org/10.1107/S2056989015017399 Text en © Stíbal et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Stíbal, David
Süss-Fink, Georg
Therrien, Bruno
Crystal structure of bis­[μ-(4-meth­oxy­phen­yl)methane­thiol­ato-κ(2) S:S]bis­[chlorido­(η(6)-1-isopropyl-4-methyl­benzene)­ruthenium(II)] chloro­form disolvate
title Crystal structure of bis­[μ-(4-meth­oxy­phen­yl)methane­thiol­ato-κ(2) S:S]bis­[chlorido­(η(6)-1-isopropyl-4-methyl­benzene)­ruthenium(II)] chloro­form disolvate
title_full Crystal structure of bis­[μ-(4-meth­oxy­phen­yl)methane­thiol­ato-κ(2) S:S]bis­[chlorido­(η(6)-1-isopropyl-4-methyl­benzene)­ruthenium(II)] chloro­form disolvate
title_fullStr Crystal structure of bis­[μ-(4-meth­oxy­phen­yl)methane­thiol­ato-κ(2) S:S]bis­[chlorido­(η(6)-1-isopropyl-4-methyl­benzene)­ruthenium(II)] chloro­form disolvate
title_full_unstemmed Crystal structure of bis­[μ-(4-meth­oxy­phen­yl)methane­thiol­ato-κ(2) S:S]bis­[chlorido­(η(6)-1-isopropyl-4-methyl­benzene)­ruthenium(II)] chloro­form disolvate
title_short Crystal structure of bis­[μ-(4-meth­oxy­phen­yl)methane­thiol­ato-κ(2) S:S]bis­[chlorido­(η(6)-1-isopropyl-4-methyl­benzene)­ruthenium(II)] chloro­form disolvate
title_sort crystal structure of bis­[μ-(4-meth­oxy­phen­yl)methane­thiol­ato-κ(2) s:s]bis­[chlorido­(η(6)-1-isopropyl-4-methyl­benzene)­ruthenium(ii)] chloro­form disolvate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4647371/
https://www.ncbi.nlm.nih.gov/pubmed/26594410
http://dx.doi.org/10.1107/S2056989015017399
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AT therrienbruno crystalstructureofbism4methoxyphenylmethanethiolatok2ssbischloridoē61isopropyl4methylbenzenerutheniumiichloroformdisolvate

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